113531-99-0Relevant academic research and scientific papers
Total Synthesis of (+/-)-Specionin
Leonard, John,Hussain, Nigel
, p. 61 - 70 (2007/10/02)
(+/-)-Specionin has been synthesized in a short, efficient sequence of reactions from (+/-)-exo,exo-6,7-bis(benzyloxy)-exo-4-(hydroxymethyl)-cis-bicyclooct-2-ene 5.The key feature of the synthesis is a 'one-pot' hydrogenolysis-cyclopentadienol clea
A GENERAL SYNTHETIC APPROACH TO OPTICALLY ACTIVE IRIDOID AGLYCONES. THE TOTAL SYNTHESES OF β-ETHYL DESCARBOMETHOXYVERBENALOL, ETHYL CATALPOL, AND (-)-SPECIONIN
Kim, Byeang Hyean,Jacobs, Patricia B.,Elliott, Richard L.,Curran, Dennis P.
, p. 3079 - 3092 (2007/10/02)
A general approach to the synthesis of iridoid aglycones is reported.A combination Claisen rearrangement/nitrile oxide cycloaddition sequence has permitted the facile annulation of a highly functionalized cyclopentane ring onto a simple glycal derived fro
IRIDOIDS: THE STRUCTURE ELUCIDATION OF SPECIONIN BASED ON CHEMICAL EVIDENCE AND 1H NMR ANALYSIS
Eycken, E. Van der,Bruyn, A. De,Eycken, J. Van der,Callant, P.,Vandewalle, M.
, p. 5385 - 5396 (2007/10/02)
The iridoid specionin is an effective antifeedant against the Eastern spruce budworm.Previous synthetic work has shown that the proposed structure was incorrect.Presently the total synthesis of the revised structure 2C is described.The structure elucidati
