113566-18-0

Basic information

• Product Name: (1S,2S)-2-isopropenyl-1-methylcyclobutanemethyl p-toluenesulfonate
• Synonyms: (1S,2S)-2-isopropenyl-1-methylcyclobutanemethyl p-toluenesulfonate
• CAS NO: 113566-18-0
• Molecular Weight: 294.415
• Mol File: 113566-18-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (1S,2S)-2-isopropenyl-1-methylcyclobutanemethyl p-toluenesulfonate(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,2S)-2-isopropenyl-1-methylcyclobutanemethyl p-toluenesulfonate(113566-18-0)
• EPA Substance Registry System: (1S,2S)-2-isopropenyl-1-methylcyclobutanemethyl p-toluenesulfonate(113566-18-0)

Safety Data

• Hazardous Substances Data: 113566-18-0(Hazardous Substances Data)

Upstream product

• 70645-37-3 Methyl (2S)-2-isopropenylcyclobutanecarboxylate 
• 113522-50-2 (1S,4R,5R)-1,4-Dimethyl-3-oxa-bicyclo[3.2.0]heptan-6-one 
• 113522-50-2 (1R,4R,5S)-1,4-dimethyl-3-oxabicyclo<3.2.0>heptan-6-one 
• 113522-51-3 (1R,4R,5R,6S)-1,4-dimethyl-3-oxabicyclo<3.2.0>heptan-6-ol 
• 113566-10-2 (1R,4R,5S)-1,4-dimethyl-3-oxabicyclo<3.2.0>heptane 
• 113522-48-8 (R)-3-(2-methyl-2-propenyloxy)butanoic acid 
• 113522-49-9 (R)-3-(2-Methyl-allyloxy)-butyryl chloride 
• 113522-47-7 (R)-3-(2-methyl-2-propenyloxy)-1-butanol 
• 99766-56-0 [(1R,2R)-2-isopropenyl-1-methyl-cyclobutyl]methanol 
• 98-59-9 p-toluenesulfonyl chloride 
• 113566-14-6 methyl (1S,2R)-2-acetyl-1-methylcyclobutanecarboxylate 
• 113566-03-3 (1S,4R,5R)-1,4-dimethyl-3-oxabicyclo<3.2.0>heptan-6-one 
• 113566-04-4 (1S,4R,5S,6R)-1,4-dimethyl-3-oxabicyclo<3.2.0>heptan-6-ol 
• 113522-53-5 (1S,4R,5R)-1,4-dimethyl-3-oxabicyclo<3.2.0>heptane 

Downstream Products

• 26532-22-9 trans-2-(1-methyl-2-(prop-1-en-2-yl)cyclobutyl)ethanol 
• 26532-22-9 (1R, 2S)-grandisol 
• 53171-65-6 trans-2-isopropenyl-1-methylcyclobutyl acetonitrile 

Relevant articles and documents

Pheromone Synthesis, CXXXVII. A New Synthesis of (+)-Grandisol

The natural and (+)-enantiomer of grandisol has been synthesized from (R)-(-)-carvone (2) by employing the intramolecular alkylation of 8 to give 9 as the key step. Key words: Anthonomus grandis; oll weevil; carvone; grandisol; pheromones

A NEW SYNTHESIS OF BOTH THE ENANTIOMERS OF GRANDISOL, THE BOLL WEEVIL PHEROMONE

The pure enantiomers of grandisol (2-isopropenyl-1-methylcyclobutane-ethanol), the pheromone component of Anthonomus grandis Boheman, were synthesized employing ethyl (R)-3-hydroxybutanoate as the single chiral source.