113600-15-0 Usage
General Description
9-Fluorobenzo[k]fluoranthene is a polycyclic aromatic hydrocarbon and a fluorinated derivative of benzo[k]fluoranthene. It is a highly toxic and potentially carcinogenic compound that is primarily produced through the incomplete combustion of organic materials such as coal, oil, and gas. Its structure consists of four fused benzene rings with a fluorine atom attached at the 9th position. 9-Fluorobenzo[k]fluoranthene is considered a persistent organic pollutant and is known to bioaccumulate in the environment and in living organisms. Exposure to this chemical has been associated with adverse health effects, including developmental and reproductive toxicity, as well as potential carcinogenicity. Consequently, it is subject to regulation and monitoring in environmental and occupational settings to minimize human and ecological exposure.
Check Digit Verification of cas no
The CAS Registry Mumber 113600-15-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,3,6,0 and 0 respectively; the second part has 2 digits, 1 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 113600-15:
(8*1)+(7*1)+(6*3)+(5*6)+(4*0)+(3*0)+(2*1)+(1*5)=70
70 % 10 = 0
So 113600-15-0 is a valid CAS Registry Number.
InChI:InChI=1/C20H11F/c21-15-8-7-13-10-18-16-5-1-3-12-4-2-6-17(20(12)16)19(18)11-14(13)9-15/h1-11H
113600-15-0Relevant articles and documents
Synthesis of Fluorinated Derivatives of Benzofluoranthene and Indenopyrene and 8,9-dihydro-8,9-epoxybenzofluoranthene
Rice, Joseph E.,Czech, Anna,Hussain, Nalband,LaVoie, Edmond J.
, p. 1775 - 1779 (2007/10/02)
The synthesis of several select fluorinated derivatives of benzofluoranthene and indenopyrene is described.In the benzofluoranthene series, the 8- and 9-fluoro derivatives have been prepared by Wittig reaction of the 1,2-bis salt of the appropriate fluorobenzene with acenaphthenequinone under phase-transfer conditions.The synthesis of 2-fluoroindenopyrene was achieved by photocyclization of 1-(β,β-difluorovinyl)benzofluoranthene followed by dehydrofluorination in methanolic sodium methoxide.This represents a new method for the construction of the indenopyrene skeleton. 8,9-Difluoroindenopyrene was prepared from 1-(2-amino-4,5-diflurophenyl)pyrene by diazotization followed by coupling in the presence of copper-bronze.In addition to these fluorinated derivatives, the synthesis of 8,9-dihydro-8,9-epoxybenzofluoranthene, a suspect ultimate tumorigenic metabolite of benzofluoranthene, is reported.This arene oxide was prepared from the trans-8,9-bromo acetate by benzylic bromination and subsequent treatment with sodium methoxide in anhydrous THF.