1136010-65-5Relevant academic research and scientific papers
Self-assembled monolayer electrode of a diiron complex with a phenoxo-based dinucleating ligand: Observation of molecular oxygen adsorption/desorption in aqueous media
Inomata, Tomohiko,Shinozaki, Kazuma,Hayashi, Yuya,Arii, Hidekazu,Funahashi, Yasuhiro,Ozawa, Tomohiro,Masuda, Hideki
, p. 392 - 394 (2008/09/19)
The phenoxo-based dinucleating ligand, 2,6-bis[bis(6-pivalamido-2- pyridylmethyl)amino-methyl]-4-aminophenol (1), and its Fe2(ii) complex, [Fe2(ii)(1)(PhCOO)2](CF3SO 3) (2), were prepared and 2 deposited on the Au surface (2/Au) is much more stable than in solution and exhibits redox behavior in aqueous media as well as reversible adsorption/desorption of oxygen at room temperature. The Royal Society of Chemistry.
