1136166-70-5Relevant academic research and scientific papers
Direct sulfonylation of Baylis-Hillman alcohols and diarylmethanols with TosMIC in ionic liquid-[Hmim]HSO4: An unexpected reaction
Garima,Srivastava, Vishnu P.,Yadav, Lal Dhar S.
experimental part, p. 4622 - 4626 (2011/09/21)
A Bronsted acidic ionic liquid-[Hmim]HSO4 promoted unexpected reaction of Baylis-Hillman alcohols and diarylmethanols with p-toluenesulfonylmethyl isocyanide (TosMIC) affording the corresponding sulfone derivatives instead of N-tosylmethyl amid
Palladium-catalyzed benzylic direct arylation of benzyl sulfones with aryl halides
Niwa, Takashi,Yorimitsu, Hideki,Oshima, Koichiro
experimental part, p. 1971 - 1976 (2009/08/07)
An effective palladium catalyst system for the direct arylation of benzyl sulfones with aryl halides has been developed. The catalytic reaction provides a facile route to diarylmethyl sulfones. The products can be transformed further via desulfonylative functionalization mediated by aluminum compounds.
