1494-29-7

Basic information

• Product Name: 1-fluoro-4-(4-tolylsulfonylmethyl)benzene
• Synonyms: 1-fluoro-4-(4-tolylsulfonylmethyl)benzene
• CAS NO: 1494-29-7
• Molecular Weight: 264.32
• Mol File: 1494-29-7.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: 1-fluoro-4-(4-tolylsulfonylmethyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-fluoro-4-(4-tolylsulfonylmethyl)benzene(1494-29-7)
• EPA Substance Registry System: 1-fluoro-4-(4-tolylsulfonylmethyl)benzene(1494-29-7)

Safety Data

• Hazardous Substances Data: 1494-29-7(Hazardous Substances Data)

Upstream product

• 1576-35-8 toluene-4-sulfonic acid hydrazide 
• 31913-41-4 6-methyl-4-tosyloxy-2(2H)-pyranone 
• 352-11-4 1-chloromethyl-4-fluorobenzene 
• 200055-89-6 4-(4-toluenesulfonyloxy)coumarin 
• 210422-66-5 4-fluorobenzaldehyde p-toluenesulfonylhydrazone 
• 459-57-4 4-fluorobenzaldehyde 
• 459-56-3 4-fluorobenzylic alcohol 
• 824-79-3 sodium 4-methylbenzenesulfinate 
• 10486-08-5 sodium p-thiocresolate 
• 1426-53-5 1-fluoro-4-((p-tolylsulfinyl)methyl)benzene 
• 1494-33-3 4-fluorobenzyl(4-methylphenyl)sulfane 

Downstream Products

• 1136166-70-5 p-fluorophenyl(phenyl)methyl p-tolyl sulfone 
• 1563173-91-0 C₂₁H₁₆F₂O₂S 

Relevant articles and documents

Kinetic resolution in vanadium-catalyzed sulfur oxidation as an efficient route to enantiopure aryl benzyl sulfoxides

Enantiopure aryl benzyl sulfoxides can be prepared using vanadium-Schiff base catalyzed sulfide oxidation and kinetic resolution of the resulting sulfoxide. The kinetic resolution can be effected in combination with asymmetric sulfide oxidation or instead starting from the racemic sulfoxide. Georg Thieme Verlag Stuttgart.

Synthesis of sulfone derivatives via palladium-catalyzed cross-coupling of benzyl trimethylammonium triflates and sulfonyl hydrazides

A palladium-catalyzed cross-coupling of benzyl trimethylammonium triflates and sulfonyl hydrazides for the synthesis of various benzyl sulfones is reported. This novel protocol shows widespread functional group tolerance, leading to the desired sulfones in moderate to excellent yields.

Zinc enolate/sulfinate prepared from a single-run reaction using zinc dust with O-tosylated 4-hydroxy coumarin and pyrone

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