113643-35-9

Upstream product

• 126394-38-5 (2Z,4S,5S,6S)-6-benzyloxymethyl-2,4-dimethyloct-2-en-5-olide 
• 67-63-0 isopropyl alcohol 
• 100-44-7 benzyl chloride 
• 126394-37-4 (3aR,6R,6aR)-5-((S)-1-Benzyloxymethyl-propyl)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxole 
• 126394-35-2 6-O-(t-butyldimethylsilyl)-3,5-dideoxy-5-C-ethyl-1,2-O-isopropylidene-3-C-methyl-β-L-allofuranose 
• 126431-34-3 (2S,3R,4S)-5-((S)-1-Benzyloxymethyl-propyl)-4-methyl-tetrahydro-furan-2,3-diol 
• 126394-36-3 (S)-2-((3aR,6R,6aR)-2,2,6-Trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-butan-1-ol 
• 110653-50-4 Toluene-4-sulfonic acid (R)-3-(tert-butyl-dimethyl-silanyloxy)-2-((3aR,6R,6aR)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-propyl ester 
• 110653-58-2 (2R,3R,4S)-4-benzyloxymethyl-3-formyloxy-2-methylhexanal 

Downstream Products

• 126394-41-0 (2S,3S,5R,6S)-2-[(1S,2R)-1-Ethyl-2-(4-methoxy-benzyloxy)-butyl]-6-isopropoxy-3,5-dimethyl-tetrahydro-pyran 
• 126455-61-6 (2S,3S,5R,6S)-2-[(1S,2S)-1-Ethyl-2-(4-methoxy-benzyloxy)-butyl]-6-isopropoxy-3,5-dimethyl-tetrahydro-pyran 
• 126394-43-2 (2R,4S,5S,6S,7R)-6-ethyl-7-(4-methoxybenzyloxy)-2,4-dimethylnonan-5-olide 
• 126575-12-0 (2R,4S,5S,6S,7S)-6-ethyl-7-(4-methoxybenzyloxy)-2,4-dimethylnonan-5-olide 
• 126394-42-1 (3R,5S,6S)-6-[(1S,2R)-1-Ethyl-2-(4-methoxy-benzyloxy)-butyl]-3,5-dimethyl-tetrahydro-pyran-2-ol 
• 126394-42-1 (3R,5S,6S)-6-[(1S,2S)-1-Ethyl-2-(4-methoxy-benzyloxy)-butyl]-3,5-dimethyl-tetrahydro-pyran-2-ol 
• 126394-40-9 (2R,4S,5S,6S,7R)-6-ethyl-5,7-isopropylidenedioxy-2,4-dimethyl-1-(4-nitrobenzyloxy)nonane 

Relevant academic research and scientific papers

STEREOSELECTIVE SYNTHESIS OF THE MIDDLE (C10-C17) AND RIGHT (C18-C30) SEGMENTS, AND THEIR COUPLING TO COMPLETE A FORMAL SYNTHESIS OF THE POLYETHER ANTIBIOTIC SALINOMYCIN

The middle (C10-C17) and right (C18-C30) segments of the polyether antibiotic salinomycin were stereoselectively synthesized from D-glucose, D-mannitol, and ethyl L-lactate.Coupling of the two segments followed by construction of the bisketal ring system gave the C10-C30 segment, which was already converted to salinomycin by Kishy.