113686-43-4

Basic information

• Product Name: <α-2H>benzenemethanethiol
• Synonyms: <α-2H>benzenemethanethiol
• CAS NO: 113686-43-4
• Molecular Weight: 125.199
• Mol File: 113686-43-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: <α-2H>benzenemethanethiol(CAS DataBase Reference)
• NIST Chemistry Reference: <α-2H>benzenemethanethiol(113686-43-4)
• EPA Substance Registry System: <α-2H>benzenemethanethiol(113686-43-4)

Safety Data

• Hazardous Substances Data: 113686-43-4(Hazardous Substances Data)

Upstream product

• 1400816-41-2 (N)-(α-deutrobenzyloxy)-2-thiopyridone 
• 1400816-39-8 (N)-(α-deutrobenzyloxy)-2-pyridone 
• 3481-15-0 (S)-[α-D]-benzyl alcohol 
• 1400816-37-6 2-(α-deutrobenzyloxy)pyridine 
• 73975-41-4 <α,α-(2)H2>toluene-α-thiol 
• 33712-34-4 benzyl-d2 chloride 
• 21175-64-4 1,1-dideuteriophenylmethanol 
• 93-58-3 benzoic acid methyl ester 
• 81572-03-4 <α-2H2>benzyl isolongifolyl thioether 
• 81572-05-6 <α-2H2>benzyl camphyl thioether 

Relevant articles and documents

Preparation of N-alkyl 2-pyridones via a lithium iodide promoted oto N-alkyl migration: Scope and mechanism

An efficient and inexpensive LiI-promoted O- to N-alkyl migration of 2-benzyloxy-, 2-allyloxy-, and 2-propargyloxypyridines and heterocycles is reported. The reaction produces the corresponding N-alkyl 2-pyridones and analogues under green, solvent-free conditions in good to excellent yields (30 examples, 20-97% yield). This method has been shown to be intermolecular and requires heat and lithium cation to occur.