113727-08-5

Basic information

• Product Name: N-(Benzyloxycarbonyl)-L-alanyl-3-O-(2,3,4-tri-O-benzoyl-β-D-xylopyranosyl)-L-seryl-glycyl-L-isoleucin-benzylester
• CAS NO: 113727-08-5
• Molecular Weight: 1015.08
• Mol File: 113727-08-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-(Benzyloxycarbonyl)-L-alanyl-3-O-(2,3,4-tri-O-benzoyl-β-D-xylopyranosyl)-L-seryl-glycyl-L-isoleucin-benzylester(CAS DataBase Reference)
• NIST Chemistry Reference: N-(Benzyloxycarbonyl)-L-alanyl-3-O-(2,3,4-tri-O-benzoyl-β-D-xylopyranosyl)-L-seryl-glycyl-L-isoleucin-benzylester(113727-08-5)
• EPA Substance Registry System: N-(Benzyloxycarbonyl)-L-alanyl-3-O-(2,3,4-tri-O-benzoyl-β-D-xylopyranosyl)-L-seryl-glycyl-L-isoleucin-benzylester(113727-08-5)

Safety Data

• Hazardous Substances Data: 113727-08-5(Hazardous Substances Data)

Upstream product

• 113727-11-0 N-(Fluorenylmethoxycarbonyl)-3-O-tert-butyl-L-seryl-glycyl-L-isoleucin-benzylester 
• 113727-13-2 N-(Benzyloxycarbonyl)-L-alanyl-3-O-tert-butyl-L-seryl-glycyl-L-isoleucin-benzylester 
• 113727-12-1 (2S,3S)-2-[2-((S)-2-Amino-3-tert-butoxy-propionylamino)-acetylamino]-3-methyl-pentanoic acid benzyl ester 
• 90315-54-1 N-(tert-Butyloxycarbonyl)glycyl-L-isoleucin-benzylester 
• 113727-10-9 Glycyl-L-isoleucin-benzylester 
• 16652-75-8 L-isoleucine benzyl ester tosylate 
• 22435-09-2 1,2,3,4-tetra-O-benzoyl-β-D-xylopyranoside 
• 113727-07-4 N-(Benzyloxycarbonyl)-L-alanyl-L-seryl-glycyl-L-isoleucin-benzylester 
• 113727-05-2 Ethyl-2,3,4-tri-O-benzoyl-1-thio-β-D-xylopyranosid 

Relevant articles and documents

Synthesis of L-Alanyl-3-O-(β-D-xylopyranosyl)-L-seryl-glycyl-L-isoleucine. Direct Glycosydation of Peptides

Glycosidation of the tetrapeptide 8 either with 1,2,3,4-tetra-O-acetyl-β-D-xylopyranose (1) under catalysis of trimethylsilyl triflate or with ethyl 2,3,4-tri-O-benzoyl-1-thio-β-D-xylopyranoside (4) using DMTST as promotor, leads to the O-glycopeptides 10 and 9.Deblocking of 10 affords the glycopeptide L-Ala-3-O-(β-D-Xylp)-L-Ser-Gly-L-Ile (11), which represents the N-terminal amino acid sequence 3 to 6 of the protein core of a proteodermantan sulfate.