113729-68-3

Upstream product

• 113729-70-7 {(1R,2S,6R)-1,2-Dimethyl-6-[4-(toluene-4-sulfonyl)-thiazol-5-ylmethyl]-cyclohexyl}-methanol 
• 113729-67-2 (4aR,8S,8aR)-8,8a-Dimethyl-octahydro-isochromene-3-thione 
• 75-05-8 acetonitrile 
• 113729-70-7 {(1S,2R,6S)-1,2-Dimethyl-6-[4-(toluene-4-sulfonyl)-thiazol-5-ylmethyl]-cyclohexyl}-methanol 
• 79243-35-9 (4aβ,8β,8aβ)-1,4,4a,5,6,7,8,8a-octahydro-8,8a-dimethyl-3H-2-benzopyran-3-one 
• 113729-67-2 (4aR,8S,8aR)-8,8a-Dimethyl-octahydro-isochromene-3-thione 
• 593-75-9 methyl isocyanate 
• 113775-84-1 (4aR,8S,8aR)-8,8a-Dimethyl-octahydro-isochromen-3-one 

Downstream Products

• 113729-69-4 (1R,2S,6R)-1,2-Dimethyl-6-thiazol-5-ylmethyl-cyclohexanecarbaldehyde 
• 3242-05-5 Eremophilan 
• 3242-05-5 Eremophilan 
• 113729-63-8 1-((1R,2S,6R)-1,2-Dimethyl-6-thiazol-5-ylmethyl-cyclohexyl)-but-2-yn-1-one 
• 113729-69-4 (1R,2S,6R)-1,2-Dimethyl-6-thiazol-5-ylmethyl-cyclohexanecarbaldehyde 
• 113729-76-3 1-((1R,2S,6R)-1,2-Dimethyl-6-thiazol-5-ylmethyl-cyclohexyl)-but-2-yn-1-ol 
• 113729-63-8 1-((1R,2S,6R)-1,2-Dimethyl-6-thiazol-5-ylmethyl-cyclohexyl)-but-2-yn-1-one 
• 3242-05-5 7-β-eremophilane 
• 3242-05-5 α-eremophilane 

Relevant academic research and scientific papers

THIAZOLES IN ORGANIC SYNTHESIS. NOVEL SYNTHESES OF MENTHANES AND EREMOPHILANES

Acetylenic thiazoles of proper design have been shown to undergo an intramolecular Diels-Alder reaction leading to fused-ring thiophene derivatives.When appropriately substituted, these latter materials can be readily converted to terpenes of the menthane

STEREOSPECIFIC TOTAL SYNTHESES OF 7α- AND 7β-EREMOPHILANE-6-ONE AND 7α- AND 7β-EREMOPHILANE

The title compounds have been prepared in a highly efficient fashion by a synthetic route involving an intramolecular Diels-Alder reaction of an acetylenic thiazole followed by reductive modification of the resulting fused-ring thiophene.