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HPLC grade Acetonitrile CAS 75-05-8, ≥99.9%
Cas No: 75-05-8
No Data 1 Metric Ton 100 Metric Ton/Week FTSCI (Hubei) Science and Technology Co.,Ltd. Contact Supplier
Acetonitrile
Cas No: 75-05-8
No Data 1 Gram No Data Hangzhou Zhongqi chem Co.,Ltd. Contact Supplier
Acetonitrile, Acetonitrile Manufacure,Good Quality Acetonitrile, Acetonitrile 75-05-8 price
Cas No: 75-05-8
No Data 1000 Kilogram Metric Ton/Day Shandong Xinhua Pharmaceutical Co.,Ltd Contact Supplier
Acetonitrile, Acetonitril, CAS: 75-05-8, Cyanomethan
Cas No: 75-05-8
No Data 1 Metric Ton Metric Ton/Day Nanjing Yuance Industry&Trade Co., Ltd. Contact Supplier
Acetonitrile
Cas No: 75-05-8
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High quality Acetonitrile supplier in China
Cas No: 75-05-8
No Data 1 Kilogram 2000 Metric Ton/Year Simagchem Corporation Contact Supplier
Top purity Acetonitrile with high quality and best price cas:75-05-8
Cas No: 75-05-8
USD $ 3.0-10.0 / Kilogram 1 Kilogram 99999 Kilogram/Year Hangzhou Dingyan Chem Co., Ltd Contact Supplier
Acetonitrile
Cas No: 75-05-8
No Data 1 Kilogram 5000 Metric Ton/Year Jinan Finer Chemical Co., Ltd Contact Supplier
High quality Acetonitrile CAS NO.75-05-8
Cas No: 75-05-8
USD $ 2.0-2.0 / Gram 100 Gram 100 Metric Ton/Month Hebei yanxi chemical co.,LTD. Contact Supplier
Acetonitrile
Cas No: 75-05-8
No Data 1 Kilogram 20 Metric Ton/Month Henan Allgreen Chemical Co.,Ltd Contact Supplier

75-05-8 Usage

InChI:InChI=1/C2H3N/c1-2-3/h1H3

75-05-8 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Alfa Aesar (36423)  Acetonitrile, ACS, 99.5+%    75-05-8 500ml 342.0CNY Detail
Alfa Aesar (36423)  Acetonitrile, ACS, 99.5+%    75-05-8 1L 506.0CNY Detail
Alfa Aesar (36423)  Acetonitrile, ACS, 99.5+%    75-05-8 4L 1340.0CNY Detail
Alfa Aesar (36423)  Acetonitrile, ACS, 99.5+%    75-05-8 *4x1L 1486.0CNY Detail
Alfa Aesar (36423)  Acetonitrile, ACS, 99.5+%    75-05-8 *4x4L 4176.0CNY Detail
Alfa Aesar (42311)  Acetonitrile, anhydrous, 99.8+%    75-05-8 250ml 178.0CNY Detail
Alfa Aesar (42311)  Acetonitrile, anhydrous, 99.8+%    75-05-8 1L 399.0CNY Detail
Alfa Aesar (42311)  Acetonitrile, anhydrous, 99.8+%    75-05-8 4L 999999.99CNY Detail
Alfa Aesar (43166)  Acetonitrile, anhydrous, 99.8+%, packaged under Argon in resealable ChemSeal? bottles    75-05-8 250ml 233.0CNY Detail
Alfa Aesar (43166)  Acetonitrile, anhydrous, 99.8+%, packaged under Argon in resealable ChemSeal? bottles    75-05-8 1L 560.0CNY Detail
Alfa Aesar (43440)  Acetonitrile, anhydrous, amine free, 99.9%    75-05-8 4L 1078.0CNY Detail
Alfa Aesar (43440)  Acetonitrile, anhydrous, amine free, 99.9%    75-05-8 *4x4L 4648.0CNY Detail

75-05-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name acetonitrile

1.2 Other means of identification

Product number -
Other names Acetonitrile

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Acetonitrile is predominantly used as a solvent in the manufacture of pharmaceuticals, for spinning fibers and for casting and molding of plastic materials, in lithium batteries, for the extraction of fatty acids from animal and vegetable oils, and in chemical laboratories for the detection of materials such as pesticide residues. Acetonitrile is also used in dyeing textiles and in coating compositions as a stabilizer for chlorinated solvents and in perfume production as a chemical intermediate.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:75-05-8 SDS

75-05-8Synthetic route

acetaldehyde
75-07-0

acetaldehyde

acetonitrile

acetonitrile

Conditions
ConditionsYield
With N-(4-sulphonic acid)butylpyridinium hydrogen sulphate; C9H13NO3S*2H3NO*H(1+)*HO4S(1-) In para-xylene at 120℃; under 760.051 Torr; for 2h; Catalytic behavior; Temperature; Time; Green chemistry;100%
With PhNHCO2NH2*TsOH In toluene for 0.5h; Condensation; elimination; Heating;87%
With K2Co4[WZn3(H2O)2][ZnW9O34]2*53H2O; ammonia; dihydrogen peroxide In water at 20℃; for 6h;100 %Spectr.
tetra-n-butylammonium cyanide
10442-39-4

tetra-n-butylammonium cyanide

methyl trifluoromethanesulfonate
333-27-7

methyl trifluoromethanesulfonate

acetonitrile
75-05-8

acetonitrile

Conditions
ConditionsYield
In chloroform-d1; dichloromethane at 20℃; for 0.0833333h; Product distribution; Further Variations:; Reaction partners;100%
NiOs3H3(1+)*C5H5(1-)*8CO*CH3CN=(C5H5)NiOs3H3(CO)8(CH3CN)

NiOs3H3(1+)*C5H5(1-)*8CO*CH3CN=(C5H5)NiOs3H3(CO)8(CH3CN)

carbon monoxide
201230-82-2

carbon monoxide

A

NiOs3H3(1+)*C5H5(1-)*9CO=(C5H5)NiOs3H3(CO)9

NiOs3H3(1+)*C5H5(1-)*9CO=(C5H5)NiOs3H3(CO)9

B

acetonitrile
75-05-8

acetonitrile

Conditions
ConditionsYield
In hexane The complex is refluxed in hexane for 3 min. A slow current of CO is passed through the soln.; The reaction soln. was filtered and concd. to small vol. under reduced pressure then subjected to preparative thin layer chromy. (silica gel; light petroleum/diethyl ether).;A 100%
B n/a
NiOs3H3(1+)*C5H5(1-)*8CO*CH3CN=(C5H5)NiOs3H3(CO)8(CH3CN)

NiOs3H3(1+)*C5H5(1-)*8CO*CH3CN=(C5H5)NiOs3H3(CO)8(CH3CN)

triphenylphosphine
603-35-0

triphenylphosphine

A

NiOs3H3(1+)*C5H5(1-)*8CO*P(C6H5)3=(C5H5)NiOs3H3(CO)8(P(C6H5)3)

NiOs3H3(1+)*C5H5(1-)*8CO*P(C6H5)3=(C5H5)NiOs3H3(CO)8(P(C6H5)3)

B

acetonitrile
75-05-8

acetonitrile

Conditions
ConditionsYield
In hexane The complex and a slight excess of Pp is refluxed in hexane (N2) for 3 min.; The reaction soln. was filtered and concd. to small vol. under reduced pressure then subjected to preparative thin layer chromy. (silica gel; light petroleum/diethyl ether).;A 100%
B n/a
ethanol
64-17-5

ethanol

acetonitrile
75-05-8

acetonitrile

Conditions
ConditionsYield
With air; silico-aluminophosphate; ammonia; water at 350℃; Product distribution; Mechanism; other reagents, var. temperature;99%
With ammonia; hydrogen at 279.84℃; Reagent/catalyst; Temperature; Flow reactor;96%
With ammonia; oxygen at 350 - 370℃; Catalytic behavior; Temperature; Reagent/catalyst; Gas phase;74%
acetamide
60-35-5

acetamide

bis(trimethylsilyl)sulphate
18306-29-1

bis(trimethylsilyl)sulphate

A

Hexamethyldisiloxane
107-46-0

Hexamethyldisiloxane

B

N-(trimethylsilyl) acetimidate

N-(trimethylsilyl) acetimidate

C

acetonitrile
75-05-8

acetonitrile

D

acetamide sulfate

acetamide sulfate

Conditions
ConditionsYield
Dehydration; sulfation; silylation; Heating;A 69%
B 5%
C 94%
D 99%
cyanoacetic acid
372-09-8

cyanoacetic acid

acetonitrile
75-05-8

acetonitrile

Conditions
ConditionsYield
copper(I) oxide In N,N-dimethyl-formamide at 110 - 120℃; for 0.5h; Product distribution / selectivity;98.3%
copper(I) oxide In dimethyl sulfoxide at 110 - 120℃; for 0.5h; Product distribution / selectivity;95%
zinc at 110 - 120℃; for 3h; Product distribution / selectivity;93.1%
iron(III) chloride In N,N-dimethyl-formamide at 110 - 120℃; for 0.5h; Product distribution / selectivity;92.7%
Raney nickel In N,N-dimethyl-formamide at 110 - 120℃; for 3h; Product distribution / selectivity;89.8%
4-decyl-4-hydroxy-3-methylisoxazoline-5-one
80490-53-5

4-decyl-4-hydroxy-3-methylisoxazoline-5-one

A

2-ketododecanoic acid
80490-57-9

2-ketododecanoic acid

B

acetonitrile
75-05-8

acetonitrile

Conditions
ConditionsYield
With 2,6-dichloro-benzonitrile In benzene for 0.5h; Heating;A 98%
B n/a
4-dodecyl-4-hydroxy-3-methylisoxazoline-5-one
80490-54-6

4-dodecyl-4-hydroxy-3-methylisoxazoline-5-one

A

2-oxotetradecanoic acid
25575-65-9

2-oxotetradecanoic acid

B

acetonitrile
75-05-8

acetonitrile

Conditions
ConditionsYield
With 2,6-dichloro-benzonitrile In benzene for 0.5h; Heating;A 98%
B n/a
fac-[Mo(CO)3(acetonitrile)3]
15038-48-9, 17731-95-2

fac-[Mo(CO)3(acetonitrile)3]

2-{N,N-bis(2-diphenylphosphinoethyl)amino}-tetrahydro-2H-1,3,2-oxazaphosphorin-2-oxide

2-{N,N-bis(2-diphenylphosphinoethyl)amino}-tetrahydro-2H-1,3,2-oxazaphosphorin-2-oxide

((+/-)-2-{N,N-bis(2-diphenylphosphinoethyl)amino}-tetrahydro-2H-1,3,2-oxazaphosphorin-2-oxide-P,P',N)-{tricarbonylmolybdenum(0)}*0.5THF

((+/-)-2-{N,N-bis(2-diphenylphosphinoethyl)amino}-tetrahydro-2H-1,3,2-oxazaphosphorin-2-oxide-P,P',N)-{tricarbonylmolybdenum(0)}*0.5THF

B

acetonitrile
75-05-8

acetonitrile

Conditions
ConditionsYield
In tetrahydrofuran exclusion of air and moisture; addn. of soln. of org. compd. in THF to soln. of Mo-compd. in THF with stirring, refluxing (8 h), cooling (room temp.); filtn., washing (pentane), drying (2 h, vac.); elem. anal.;A 96.2%
B n/a
fac-[W(CO)3(MeCN)3]
16800-47-8, 30958-95-3

fac-[W(CO)3(MeCN)3]

2-{N,N-bis(2-diphenylphosphinoethyl)amino}-tetrahydro-2H-1,3,2-oxazaphosphorin-2-oxide

2-{N,N-bis(2-diphenylphosphinoethyl)amino}-tetrahydro-2H-1,3,2-oxazaphosphorin-2-oxide

((+/-)-2-{N,N-bis(2-diphenylphosphinoethyl)amino}-tetrahydro-2H-1,3,2-oxazaphosphorin-2-oxide-P,P',N)-{tricarbonyltungsten(0)}*0.5THF

((+/-)-2-{N,N-bis(2-diphenylphosphinoethyl)amino}-tetrahydro-2H-1,3,2-oxazaphosphorin-2-oxide-P,P',N)-{tricarbonyltungsten(0)}*0.5THF

B

acetonitrile
75-05-8

acetonitrile

Conditions
ConditionsYield
In tetrahydrofuran exclusion of air and moisture; addn. of soln. of org. compd. in THF to soln. of W-compd. in THF with stirring, refluxing (8 h), cooling (room temp.); filtn., washing (pentane), drying (2 h, vac.); elem. anal.;A 96%
B n/a
acetamide
60-35-5

acetamide

acetonitrile
75-05-8

acetonitrile

Conditions
ConditionsYield
With zeolite HZSM-5 In water at 350℃; Product distribution; var. zeolites; also at 400 deg C;95%
With sulfur dioxide; oxygen at 65℃; for 0.666667h; Temperature;95%
at 215℃; for 1h; Temperature;83%
acetic acid
64-19-7

acetic acid

acetonitrile
75-05-8

acetonitrile

Conditions
ConditionsYield
With ammonium hydroxide at 500 - 600℃; for 3h;95%
With ammonia; silica gel at 500℃;
With iron(III) oxide; ammonia at 425℃;
mesitylenesulfonylhydroxylamine
36016-40-7

mesitylenesulfonylhydroxylamine

acetaldehyde
75-07-0

acetaldehyde

A

mesitylene sulfonic acid
3453-83-6

mesitylene sulfonic acid

B

acetonitrile
75-05-8

acetonitrile

Conditions
ConditionsYield
In dichloromethane at 20℃; for 16h; Product distribution;A 95%
B n/a
3-bromo-3-methyldiazirine
4222-23-5

3-bromo-3-methyldiazirine

acetonitrile
75-05-8

acetonitrile

Conditions
ConditionsYield
With tetrabutylammoniun azide at -1.3℃; Rate constant;95%
2,4-bis(4-ethoxycarbonylphenyl)-2,4-dithioxo-1,3,2λ5,4λ5-dithiadiphosphetane
30043-13-1

2,4-bis(4-ethoxycarbonylphenyl)-2,4-dithioxo-1,3,2λ5,4λ5-dithiadiphosphetane

N,N-bis(trimethylsilyl)acetamide
10416-58-7

N,N-bis(trimethylsilyl)acetamide

A

O,S-bis(trimethylsilyl)-4-ethoxyphenyldithiophosphonate
138172-30-2

O,S-bis(trimethylsilyl)-4-ethoxyphenyldithiophosphonate

B

acetonitrile
75-05-8

acetonitrile

Conditions
ConditionsYield
at 50℃; for 2.5h;A 80.8%
B 95%
L-alanin
56-41-7

L-alanin

acetonitrile
75-05-8

acetonitrile

Conditions
ConditionsYield
With ammonium bromide In methanol; water Electrochemical reaction;94%
With perchloric acid; N,N-Dichlorobenzenesulfonamide In methanol; water at 29.9℃; Rate constant; Kinetics; Thermodynamic data; other amino acids; var. temp. and conditions; ΔH(excit.), ΔS(excit.), ΔG(excit.), Ea; equilibrium constant;
With perchloric acid; N,N-Dichlorobenzenesulfonamide; sodium perchlorate In water; acetic acid at 39.9℃; Rate constant; Kinetics; Thermodynamic data; var. temp. and conditions; Ea, ΔH(excit.), ΔS(excit.), ΔG(excit.);
sodium cyanide
143-33-9

sodium cyanide

dimethyl sulfate
77-78-1

dimethyl sulfate

acetonitrile
75-05-8

acetonitrile

Conditions
ConditionsYield
With PEG400 for 5h; Heating;94%
carbonyl(acetonitrile)bis(1,2-bis(dimethylphosphino)ethane)manganese(I) tetraphenylborate
133672-21-6

carbonyl(acetonitrile)bis(1,2-bis(dimethylphosphino)ethane)manganese(I) tetraphenylborate

benzonitrile
100-47-0

benzonitrile

carbonyl(benzonitrile)bis(1,2-bis(dimethylphosphino)ethane)manganese(I) tetraphenylborate
133672-19-2

carbonyl(benzonitrile)bis(1,2-bis(dimethylphosphino)ethane)manganese(I) tetraphenylborate

B

acetonitrile
75-05-8

acetonitrile

Conditions
ConditionsYield
In benzonitrile at 70°C for 1.5 h; added diethyl ether; pptd.;A n/a
B 94%
4-benzyl-4-hydroxy-3-methylisoxazoline-5-one

4-benzyl-4-hydroxy-3-methylisoxazoline-5-one

A

B

acetonitrile
75-05-8

acetonitrile

Conditions
ConditionsYield
With 2,6-dichloro-benzonitrile In benzene for 1h; Heating;A 92.7%
B n/a
tetrakis(acetonitrile)palladium(II) tetrafluoroborate
21797-13-7

tetrakis(acetonitrile)palladium(II) tetrafluoroborate

diethylamine
109-89-7

diethylamine

trans-bis(N,N-diethylcarbamato)bis(diethylamine)palladium(II)
127469-78-7

trans-bis(N,N-diethylcarbamato)bis(diethylamine)palladium(II)

B

diethylammonium tetrafluoroborate

diethylammonium tetrafluoroborate

C

acetonitrile
75-05-8

acetonitrile

Conditions
ConditionsYield
With CO2 In toluene satn. of NHEt2 in toluene with CO2 at room temp. and atm. pressure, addn. of the Pd compd. and stirring for 8 h; concn. (vac.), filtn. under CO2, evapn. to dryness (vac.) and recrystn. from n-heptane; elem. anal.;A 92%
B n/a
C n/a
(3aR*)-pentacarbonyl[thioacetimidic acid (3-ethoxy-4,5,6,7,-tetrahydro-3aH-inden-1-yl) ester-N]tungsten

(3aR*)-pentacarbonyl[thioacetimidic acid (3-ethoxy-4,5,6,7,-tetrahydro-3aH-inden-1-yl) ester-N]tungsten

A

(3aR*,7aS*)-pentacarbonyl(3-ethoxy-3a,4,5,6,7,7a-hexahydroindene-3-thione-S)tungsten

(3aR*,7aS*)-pentacarbonyl(3-ethoxy-3a,4,5,6,7,7a-hexahydroindene-3-thione-S)tungsten

B

acetonitrile
75-05-8

acetonitrile

Conditions
ConditionsYield
In dichloromethane decomposition in dichloromethane soln. at 50°C for 5 h;A 92%
B n/a
N,N-bis(trimethylsilyl)acetamide
10416-58-7

N,N-bis(trimethylsilyl)acetamide

A

O,S-bis(trimethylsilyl)-4-methoxyphenyldithiophosphonate
138172-29-9

O,S-bis(trimethylsilyl)-4-methoxyphenyldithiophosphonate

B

acetonitrile
75-05-8

acetonitrile

Conditions
ConditionsYield
at 20℃; for 168h;A 68.2%
B 90.9%
NiOs3H3(1+)*C5H5(1-)*8CO*CH3CN=(C5H5)NiOs3H3(CO)8(CH3CN)

NiOs3H3(1+)*C5H5(1-)*8CO*CH3CN=(C5H5)NiOs3H3(CO)8(CH3CN)

A

NiOs3H3(1+)*C5H5(1-)*9CO=(C5H5)NiOs3H3(CO)9

NiOs3H3(1+)*C5H5(1-)*9CO=(C5H5)NiOs3H3(CO)9

B

NiOs3H3(1+)*C5H5(1-)*8CO*C2(P(C6H5)2)2=(C5H5)NiOs3H3(CO)8(C2(P(C6H5)2)2)

NiOs3H3(1+)*C5H5(1-)*8CO*C2(P(C6H5)2)2=(C5H5)NiOs3H3(CO)8(C2(P(C6H5)2)2)

C

acetonitrile
75-05-8

acetonitrile

Conditions
ConditionsYield
In hexane The complex and a slight excess of C2(PPh2)2 were refluxed in hexane (N2) for 3 min. Decompn. was observed.; The reaction soln. was filtered and concd. to small vol. under reduced pressure then subjected to preparative thin layer chromy. (silica gel; light petroleum/diethyl ether).;A n/a
B 90%
C n/a
(3aR*)-pentacarbonyl[thioacetimidic acid (3-ethoxy-4,5,6,7,8-pentahydro-3aH-azulen-1-yl) ester-N]tungsten

(3aR*)-pentacarbonyl[thioacetimidic acid (3-ethoxy-4,5,6,7,8-pentahydro-3aH-azulen-1-yl) ester-N]tungsten

A

(3aR*,8aS*)-pentacarbonyl(3-ethoxy-4,5,6,7,8,8a-hexahydro-3aH-azulene-1-thione-S)tungsten

(3aR*,8aS*)-pentacarbonyl(3-ethoxy-4,5,6,7,8,8a-hexahydro-3aH-azulene-1-thione-S)tungsten

B

acetonitrile
75-05-8

acetonitrile

Conditions
ConditionsYield
In dichloromethane decomposition in dichloromethane soln. at 50°C for 5 h;A 90%
B n/a
[(η5-C5H2-1,2,4-Me3)2Hf(CN)](μ-O)[(η5-C5H2-1,2,4-Me3)2Hf(NCO)]

[(η5-C5H2-1,2,4-Me3)2Hf(CN)](μ-O)[(η5-C5H2-1,2,4-Me3)2Hf(NCO)]

methyl trifluoromethanesulfonate
333-27-7

methyl trifluoromethanesulfonate

A

[(η5-C5H2-1,2,4-Me3)2Hf(OTf)](μ-O)[(η5-C5H2-1,2,4-Me3)2Hf(NCO)]

[(η5-C5H2-1,2,4-Me3)2Hf(OTf)](μ-O)[(η5-C5H2-1,2,4-Me3)2Hf(NCO)]

B

acetonitrile
75-05-8

acetonitrile

Conditions
ConditionsYield
In toluene at 23℃; for 18h;A 90%
B n/a
anethole
104-46-1

anethole

A

B

acetonitrile
75-05-8

acetonitrile

Conditions
ConditionsYield
With [bis(acetoxy)iodo]benzene; ammonium bicarbonate In methanol; water at 36℃; for 12h; Sealed tube;A 90%
B n/a
tetrakis(acetonitrile)copper(I)tetrafluoroborate

tetrakis(acetonitrile)copper(I)tetrafluoroborate

bis(cyclopentadienyl)(phenylthiolato)2molybdenum

bis(cyclopentadienyl)(phenylthiolato)2molybdenum

A

{(C5H5)2Mo(μ-SPh)2Cu(PPh3)2}BF4

{(C5H5)2Mo(μ-SPh)2Cu(PPh3)2}BF4

B

acetonitrile
75-05-8

acetonitrile

Conditions
ConditionsYield
With P(C6H5)3 In acetone under N2, Cu-compd. in acetone and PPh3 stirred for 15 min at room temp., addn. to a soln. of Mo-compd. in acetone, stirred for 2 h; filtered, concd. in vac., addn. of ether, pptn. washed with benzene and ether, recrystn. (CH2Cl2/ether); elem. anal.;A 88%
B n/a
4,7-diaza-3,8-di(1-methylpropyl)deca-2,8-diene-1,10-dinitrile
87439-92-7

4,7-diaza-3,8-di(1-methylpropyl)deca-2,8-diene-1,10-dinitrile

A

3-cyanomethylene-2-ethyl-2-methyl-4-(1-methylpropylidene)cyclobutanecarbonitrile
29782-33-0

3-cyanomethylene-2-ethyl-2-methyl-4-(1-methylpropylidene)cyclobutanecarbonitrile

B

2-(1-methylpropyl)-2-imidazoline
54956-98-8

2-(1-methylpropyl)-2-imidazoline

C

acetonitrile
75-05-8

acetonitrile

Conditions
ConditionsYield
at 300℃;A 0.45 g
B 87%
C 73%
benzoic acid methyl ester
93-58-3

benzoic acid methyl ester

acetonitrile
75-05-8

acetonitrile

Benzoylacetonitrile
614-16-4

Benzoylacetonitrile

Conditions
ConditionsYield
Stage #1: acetonitrile With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h;
Stage #2: benzoic acid methyl ester In tetrahydrofuran; hexane at -78 - -45℃; for 3h;
100%
Stage #1: acetonitrile With sodium hydride In dimethyl sulfoxide at 20℃; for 0.333333h; Cooling with ice;
Stage #2: benzoic acid methyl ester In dimethyl sulfoxide at 20℃; for 2h;
98%
Stage #1: acetonitrile With sodium hydride In dimethyl sulfoxide; mineral oil at 20℃; for 0.333333h; Cooling with ice;
Stage #2: benzoic acid methyl ester In mineral oil for 2h;
98%
acetonitrile
75-05-8

acetonitrile

tert-butyl alcohol
75-65-0

tert-butyl alcohol

N-tert-butylacetamide
762-84-5

N-tert-butylacetamide

Conditions
ConditionsYield
With Selectfluor; Diphenylphosphine oxide at 60℃; for 24h; Ritter Amidation;100%
With 1-methyl-3-(4-sulfonylbutyl)-1H-imidazol-3-ium trifluoromethanesulfonate at 70℃; for 8h; Ritter reaction; Inert atmosphere; Ionic liquid;95%
With HClO4-functionalized silica-coated magnetic nanoparticles [γ-Fe2O3@SiO2-HClO4] at 20℃; for 4h; Ritter reaction; Neat (no solvent);94%
acetonitrile
75-05-8

acetonitrile

4-amino-2,6-dimethylpyrimidine
461-98-3

4-amino-2,6-dimethylpyrimidine

Conditions
ConditionsYield
With potassium tert-butylate; dihydrogen peroxide In water at 120℃; for 12h; Sealed tube;100%
With magnesium at 120 - 130℃; for 14h;93%
With sodium methylate at 150℃; for 14h;90%
Conditions
ConditionsYield
With hydroxylamine monohydrate In ethanol at 90℃; for 3h; Sealed tube;100%
With hydroxylamine hydrochloride; potassium carbonate In ethanol for 20h; Reflux;82.4%
With hydroxylamine hydrochloride; sodium carbonate In ethanol; water at 55℃; for 0.5h; Sonication;81%
diphenyl acetylene
501-65-5

diphenyl acetylene

acetonitrile
75-05-8

acetonitrile

2-methyl-4,5-diphenyloxazole
14224-99-8

2-methyl-4,5-diphenyloxazole

Conditions
ConditionsYield
Stage #1: acetonitrile With tetrabutylammonium tetrafluoroborate; water; iodine; acetic acid for 2.68333h; Electrolysis;
Stage #2: diphenyl acetylene for 1.08333h; Reagent/catalyst; Electrolysis;
100%
With 1-Chloro-4-iodobenzene; bis(trifluoromethanesulfonyl)amide; 3-chloro-benzenecarboperoxoic acid at 20℃; for 24h; Inert atmosphere; regioselective reaction;81%
With trifluorormethanesulfonic acid; benzenetellurinyl trifluoromethanesulfonate for 2h; Heating;75%
With iodosylbenzene; bis(trifluoromethanesulfonyl)amide at 0 - 20℃; for 20h; Reagent/catalyst; Temperature; Time; Inert atmosphere;73%
With iodosylbenzene; bis(trifluoromethanesulfonyl)amide at 20℃; for 20h; Reagent/catalyst; Temperature; regioselective reaction;73%
2-Adamantanone
700-58-3

2-Adamantanone

acetonitrile
75-05-8

acetonitrile

2-adamantaneylideneacetonitrile
38121-89-0

2-adamantaneylideneacetonitrile

Conditions
ConditionsYield
With potassium hydroxide In dimethyl sulfoxide for 10h; Reflux;100%
With potassium hydroxide for 12h; Heating;86%
With perhydrodibenzo-18-crown-6; potassium hydroxide Heating;80%
With potassium hydroxide In dimethyl sulfoxide for 10h; Reflux;
α-hydroxyhippuric acid
19791-95-8, 19791-97-0, 16555-77-4

α-hydroxyhippuric acid

acetonitrile
75-05-8

acetonitrile

1-Benzamido-1-acetamidoacetic acid
128600-16-8

1-Benzamido-1-acetamidoacetic acid

Conditions
ConditionsYield
With trichlorophosphate at 80℃; for 0.08h;100%
acetonitrile
75-05-8

acetonitrile

methyl trifluoromethanesulfonate
333-27-7

methyl trifluoromethanesulfonate

N-methylacetonitrilium trifluoromethanesulphonate
76893-86-2

N-methylacetonitrilium trifluoromethanesulphonate

Conditions
ConditionsYield
for 18h; Ambient temperature;100%
94%
In dichloromethane at 70 - 80℃; for 0.166667h; Product distribution; other temperature, time; a series of nitriles investigated;78%
In benzene for 0.333333h; Heating;57%
acetonitrile
75-05-8

acetonitrile

ethanamine hydrochloride
557-66-4

ethanamine hydrochloride

Conditions
ConditionsYield
With hydrogenchloride; hydrogen In propan-1-ol; water at 60 - 70℃; under 375.038 Torr; for 18h; Flow reactor;100%
Stage #1: acetonitrile With cobalt pivalate; 1,1,3,3-Tetramethyldisiloxane; tert-butylisonitrile at 80℃; for 24h;
Stage #2: With hydrogenchloride In diethyl ether at 20℃; for 0.5h; Catalytic behavior; Reagent/catalyst; Temperature; Time;
96%
With hydrogenchloride; lithium borohydride; chloro-trimethyl-silane In tetrahydrofuran for 24h; Ambient temperature;75%
Stage #1: acetonitrile With ammonium hydroxide; hydrogen; cobalt(II) diacetate tetrahydrate; zinc trifluoromethanesulfonate; zinc In methanol at 120℃; under 30003 Torr; for 15h; Sealed tube; Autoclave;
Stage #2: With hydrogenchloride In diethyl ether
48%
Stage #1: acetonitrile With [2,6-η6:η1-bis(2,4,6-trimethylphenyl)phenylthiolato]triethylphosphineruthenium(II)tetrakis[3,5-bis(trifluoromethyl)phenyl]borate; diethylphenylsilane at 20℃; for 18h; Glovebox; Inert atmosphere;
Stage #2: With hydrogenchloride In diethyl ether at 20℃; for 1h; Glovebox; Inert atmosphere;
34%
1-Phenyl-2-propyn-1-ol
4187-87-5

1-Phenyl-2-propyn-1-ol

acetonitrile
75-05-8

acetonitrile

N-(α-phenylpropargyl)acetamide
123772-66-7

N-(α-phenylpropargyl)acetamide

Conditions
ConditionsYield
With sulfuric acid; sodium sulfate at -25 - 20℃; for 48h; Inert atmosphere;100%
With sulfuric acid; sodium sulfate at -20 - 20℃; for 48h; Inert atmosphere;97%
With sulfuric acid; sodium sulfate at -20 - 20℃; for 48h; Substitution; Ritter reaction;91%
tris(pentafluorophenyl)borate
1109-15-5

tris(pentafluorophenyl)borate

acetonitrile
75-05-8

acetonitrile

tris(perfluorophenyl)borane-acetonitrile adduct
212619-93-7

tris(perfluorophenyl)borane-acetonitrile adduct

Conditions
ConditionsYield
Inert atmosphere; Sealed tube;100%
In pentane Ar-atmosphere; pptn. Lewis base dropwise addn., stirring (room temp., 2 h); filtering, washing (pentane), drying (vac.); elem. anal.;94%
In acetonitrile; pentane stirring at room temp. for 1 h; evapn., drying (vac., 1E-5 Torr, room temp.); elem. anal.;89%
In pentane Schlenk techniques; MeCN added to suspn. of B(C6F5)3 (molar ratio 3.4:1) in pentane; stirred for 1 h; filtered; ppt. dried in vac.;78%
With 2,6-dimethylpyridine In toluene N2 glove box; mixt. 2,6-lutidine, B(C6F5)3 and MeCN (1:1:1 mol) in toluene stirred for 20 min; evapd. (vac.); NMR;
4-methoxy-aniline
104-94-9

4-methoxy-aniline

acetonitrile
75-05-8

acetonitrile

A

N,N-diethyl-4-methoxyaniline
15144-80-6

N,N-diethyl-4-methoxyaniline

B

4-methoxy-N-ethylaniline
104-48-3

4-methoxy-N-ethylaniline

Conditions
ConditionsYield
With ammonium formate; palladium on activated charcoal In water at 20℃; for 0.7h;A n/a
B 100%
With palladium 10% on activated carbon; hydrogen In methanol at 20℃; under 760.051 Torr; for 18h;
1-amino-3-methylbenzene
108-44-1

1-amino-3-methylbenzene

acetonitrile
75-05-8

acetonitrile

A

N-ethyl-m-toulidine
102-27-2

N-ethyl-m-toulidine

B

N,N-diethyl-m-toluidine

N,N-diethyl-m-toluidine

Conditions
ConditionsYield
With ammonium formate; palladium on activated charcoal In water at 20℃; for 0.8h;A 100%
B n/a
3,4,5-Trimethoxyaniline
24313-88-0

3,4,5-Trimethoxyaniline

acetonitrile
75-05-8

acetonitrile

N-ethyl-3,4,5-trimethoxyaniline
163629-15-0

N-ethyl-3,4,5-trimethoxyaniline

Conditions
ConditionsYield
With hydrogen; palladium on activated charcoal In methanol at 20℃; for 22h;100%
With palladium 10% on activated carbon; hydrogen In methanol at 20℃; under 760.051 Torr; for 22h;100%
allyl bromide
106-95-6

allyl bromide

acetonitrile
75-05-8

acetonitrile

2,2-bis(2-propenyl)-4-pentenenitrile
872278-20-1

2,2-bis(2-propenyl)-4-pentenenitrile

Conditions
ConditionsYield
Multistep reaction;100%
Stage #1: acetonitrile With lithium diisopropyl amide In tetrahydrofuran at -78℃; for 0.25h;
Stage #2: allyl bromide In tetrahydrofuran at -78 - 20℃;
Stage #3: allyl bromide Further stages;
81%
Stage #1: acetonitrile With lithium diisopropyl amide In tetrahydrofuran at -78℃;
Stage #2: allyl bromide In tetrahydrofuran at 20℃;
Chlor(dimesityl)silan
50490-74-9

Chlor(dimesityl)silan

acetonitrile
75-05-8

acetonitrile

bis(2,4,6-trimethylphenyl)silanol
88589-59-7

bis(2,4,6-trimethylphenyl)silanol

Conditions
ConditionsYield
Stage #1: dimesitylchlorosilane; acetonitrile With n-butyllithium In tetrahydrofuran at -78 - 20℃;
Stage #2: With water; hydroxide at 22℃; Further stages.;
100%
methyl 3-methylbutanoate
556-24-1

methyl 3-methylbutanoate

acetonitrile
75-05-8

acetonitrile

5-methyl-3-oxo-hexanenitrile
64373-43-9

5-methyl-3-oxo-hexanenitrile

Conditions
ConditionsYield
With sodium hydride In tetrahydrofuran for 5.5h; Heating / reflux;100%
With sodium hydride In tetrahydrofuran for 5.5h; Heating / reflux;100%
With sodium hydride In tetrahydrofuran; mineral oil at 70℃; for 15h;98%
2-bromo-3-picoline
3430-17-9

2-bromo-3-picoline

acetonitrile
75-05-8

acetonitrile

(3-methyl-pyridin-2-yl)-acetonitrile
38203-11-1

(3-methyl-pyridin-2-yl)-acetonitrile

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran; hexanes at -78℃; for 2.08333h;100%
With n-butyllithium In tetrahydrofuran; hexane at -78 - 20℃; for 4h;91%
palladium(0)bis(tricyclohexylphosphine)
33309-88-5

palladium(0)bis(tricyclohexylphosphine)

acetonitrile
75-05-8

acetonitrile

N,N'-dimethylaniliniumtetrakis(pentafluorophenyl)borate

N,N'-dimethylaniliniumtetrakis(pentafluorophenyl)borate

trans-[(Cy3P)2Pd(H)(MeCN)][B(C6F5)4]

trans-[(Cy3P)2Pd(H)(MeCN)][B(C6F5)4]

Conditions
ConditionsYield
at 20℃; Product distribution / selectivity;100%
bis(tricyclohexylphosphine)palladium diacetate
545401-38-5, 59840-38-9

bis(tricyclohexylphosphine)palladium diacetate

lithium(etherate)2.5 tetrakis(pentafluorophenyl)borate

lithium(etherate)2.5 tetrakis(pentafluorophenyl)borate

acetonitrile
75-05-8

acetonitrile

trans-[Pd(OAc)(P(Cy)3)2(MeCN)][B(C6F5)4]

trans-[Pd(OAc)(P(Cy)3)2(MeCN)][B(C6F5)4]

Conditions
ConditionsYield
for 3h;100%
Pd(O2CPh)2(P(Cy)3)2
164019-42-5

Pd(O2CPh)2(P(Cy)3)2

lithium(etherate)2.5 tetrakis(pentafluorophenyl)borate

lithium(etherate)2.5 tetrakis(pentafluorophenyl)borate

acetonitrile
75-05-8

acetonitrile

trans-(acetonitrile)(benzoato)bis(tricyclohexylphosphine)palladium(II) tetrakis(pentafluorophenyl)borate

trans-(acetonitrile)(benzoato)bis(tricyclohexylphosphine)palladium(II) tetrakis(pentafluorophenyl)borate

Conditions
ConditionsYield
In dichloromethane for 15h;100%
Pd(O2C-t-Bu)2(P(Cy)3)2
851368-19-9

Pd(O2C-t-Bu)2(P(Cy)3)2

lithium(etherate)2.5 tetrakis(pentafluorophenyl)borate

lithium(etherate)2.5 tetrakis(pentafluorophenyl)borate

acetonitrile
75-05-8

acetonitrile

trans-(acetonitrile)(trimethylacetato)bis(tricyclohexylphosphine)palladium(II) tetrakis(pentafluorophenyl)borate

trans-(acetonitrile)(trimethylacetato)bis(tricyclohexylphosphine)palladium(II) tetrakis(pentafluorophenyl)borate

Conditions
ConditionsYield
In dichloromethane for 5h;100%
ethyl trifluoroacetate,
383-63-1

ethyl trifluoroacetate,

acetonitrile
75-05-8

acetonitrile

3-cyano-1,1,1-trifluoroacetone
110234-68-9

3-cyano-1,1,1-trifluoroacetone

Conditions
ConditionsYield
With sodium hydride In tetrahydrofuran at 70℃; for 15h; Reflux;100%
Stage #1: acetonitrile With sodium hydride In 1,4-dioxane at 0 - 20℃;
Stage #2: ethyl trifluoroacetate, In 1,4-dioxane at 20 - 100℃; for 5.5h;
74%
With sodium hydride In tetrahydrofuran Heating / reflux;
acetonitrile
75-05-8

acetonitrile

methyl 9-[(tert-butyldimethylsilyl)oxy]-10-oxo-12(Z),15(Z)-octadecadienate
359643-46-2

methyl 9-[(tert-butyldimethylsilyl)oxy]-10-oxo-12(Z),15(Z)-octadecadienate

(12Z,15Z)-methyl 9-hydroxy-10-oxooctadeca-12,15-dienoate
359643-47-3

(12Z,15Z)-methyl 9-hydroxy-10-oxooctadeca-12,15-dienoate

Conditions
ConditionsYield
With hydrogen fluoride100%
Ac2 O

Ac2 O

acetonitrile
75-05-8

acetonitrile

MORPHIN
57-27-2

MORPHIN

3-acetylmorphine

3-acetylmorphine

Conditions
ConditionsYield
With sodium hydrogencarbonate In methanol; dichloromethane; water; toluene100%
6-methoxy-2-naphthoic acid methyl ester
5043-02-7

6-methoxy-2-naphthoic acid methyl ester

acetonitrile
75-05-8

acetonitrile

3-(6-methoxy-naphthalen-2-yl)-3-oxo-propionitrile
92163-27-4

3-(6-methoxy-naphthalen-2-yl)-3-oxo-propionitrile

Conditions
ConditionsYield
Stage #1: 6-methoxy-2-naphthoic acid methyl ester; acetonitrile With sodium hydride In toluene at 90℃; for 18h;
Stage #2: With hydrogenchloride; water In toluene pH=3;
100%
Stage #1: 6-methoxy-2-naphthoic acid methyl ester With sodium hydride In toluene at 90℃;
Stage #2: acetonitrile In toluene at 90℃;
Stage #3: With hydrogenchloride In water pH=3;
100%
Stage #1: 6-methoxy-2-naphthoic acid methyl ester; acetonitrile With sodium hydride In toluene at 90℃; for 18h;
Stage #2: With hydrogenchloride; water pH=3;
100%
methyl 3,4-dimethoxybenzoate
2150-38-1

methyl 3,4-dimethoxybenzoate

acetonitrile
75-05-8

acetonitrile

ω-cyano-3,4-dimethoxyacetophenone
4640-69-1

ω-cyano-3,4-dimethoxyacetophenone

Conditions
ConditionsYield
Stage #1: acetonitrile With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h;
Stage #2: methyl 3,4-dimethoxybenzoate In tetrahydrofuran; hexane at -78 - -45℃; Further stages.;
100%
With sodium hydride In tetrahydrofuran for 6h; Cooling with ice; Reflux;96%
4-hydroxy[1]benzopyran-2-one
1076-38-6

4-hydroxy[1]benzopyran-2-one

4-bromo-benzaldehyde
1122-91-4

4-bromo-benzaldehyde

acetonitrile
75-05-8

acetonitrile

N-[(4-bromophenyl)(4-hydroxy-2-oxo-2H-chromen-3-yl)methyl]acetamide
1092452-47-5

N-[(4-bromophenyl)(4-hydroxy-2-oxo-2H-chromen-3-yl)methyl]acetamide

Conditions
ConditionsYield
With chlorosulfonic acid at 20℃; for 1h;100%
Stage #1: 4-hydroxy[1]benzopyran-2-one; 4-bromo-benzaldehyde; acetonitrile With phosphorus pentaoxide; Hexamethyldisiloxane at 20℃; for 3h;
Stage #2: With water cooling; Further stages.;
90%

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