113798-80-4Relevant academic research and scientific papers
Application of pig liver esterase catalyzed transesterification in organic media to the kinetic resolution of glycerol derivatives
Jungen, Manfred,Gais, Hans-Joachim
, p. 3747 - 3758 (1999)
The PLE/MPEG catalyzed transesterification of the glycerol ketals rac-1a and rac-1d-f with vinyl propionate in toluene proceeded with good selectivities (E=24-34) and gave the enantiomerically enriched S-alcohols 1a and 1d-f, and the S-esters 2a and 2d-f. High selectivities (E=99 and E≥200) were observed in the transesterification of the glycerol ether rac-3 and its desoxy analog rac-5, both having a secondary hydroxy group, with PLE/MPEG. In transesterifications in organic media PLE exhibited a much higher enantioselectivity than in hydrolysis in water.
Organocatalytic kinetic resolution of racemic primary alcohols using a chiral 1,2-diamine derived from (S)-proline
Terakado, Dai,Koutaka, Hitomi,Oriyama, Takeshi
, p. 1157 - 1165 (2007/10/03)
A highly efficient and good enantioselective organocatalytic asymmetric acylation of racemic primary alcohols with acyl chlorides has been achieved catalyzed by a chiral 1,2-diamine derived from (S)-proline.
EFFICIENT RESOLUTION OF SECONDARY ALCOHOLS, CYANOHYDRINS, AND GLYCEROL ACETALS BY COMPLEXATION WITH THE HOST DERIVED FROM TARTARIC ACID
Toda, Fumio,Matsuda, Shotaro,Tanaka, Koichi
, p. 983 - 986 (2007/10/02)
Some title hydroxy compounds were resolved efficiently by complexation with the host compounds derived from tartaric acid.
