1138162-59-0

Basic information

• Product Name: C₁₈H₂₉BO₃Si
• Synonyms: C₁₈H₂₉BO₃Si
• CAS NO: 1138162-59-0
• Molecular Weight: 332.323
• Mol File: 1138162-59-0.mol

Chemical Properties

• CAS DataBase Reference: C₁₈H₂₉BO₃Si(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₈H₂₉BO₃Si(1138162-59-0)
• EPA Substance Registry System: C₁₈H₂₉BO₃Si(1138162-59-0)

Safety Data

• Hazardous Substances Data: 1138162-59-0(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 906066-08-8 trimethyl(3-phenylprop-2-ynyloxy)silane 
• 25015-63-8 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane 
• 118665-81-9 trimethyl((1-phenylprop-2-yn-1-yl)oxy)silane 

Downstream Products

• 1370723-34-4 (E)-ethyl [1-phenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)allyl] carbonate 
• 1370723-35-5 (E)-1-phenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)allyl phenylcarbamate 
• 167896-49-3 (E)-1-phenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)prop-2-en-1-ol 

Relevant articles and documents

Synthesis of (Z)-alkene-containing linear conjugated dienyl homoallylic alcohols by a palladium-catalyzed three-component reaction

A synthesis of (Z)-alkene-containing linear conjugated dienyl homoallylic alcohols by using a palladium-catalyzed three-component reaction has been developed. This method shows good functional-group compatibility and generality, with high diastereoselectivity. Additionally, in many cases, the present method controls the alkene stereochemistry of the newly formed C-C bond and overcomes the inherent preference for (E)-alkene formation, giving (Z, E)- and (Z, Z)-products.

Cyclopropanation of strained alkenes by palladium-catalyzed reaction of 3-trimethylsilyl- or 3-pinacolatoboryl-1-arylallyl acetates

The palladium-catalyzed cyclopropanation of strained alkenes with 3-trimethylsilyl- or 3-pinacolatoboryl-1-arylallyl acetate derivatives is described. This reaction gives cyclopropanation products in good to high yields with a single diastereomer, and the key step is likely to involve the formation of a palladacyclobutene complex from the α-trimethylsilyl- or α-pinacolatoboryl-σ-allylpalladium complex. Copyright

SN2′ boron-mediated Mitsunobu reactions - A new one-pot three-component synthesis of substituted enamides and enol benzoates

The conversion of (3-hydroxy-1-propen-1-yl)boronates to substituted enamides and enol benzoates is readily achieved in a one-pot procedure consisting of a regiocontrolled Mitsunobu reaction with convenient nucleophiles, followed by allylboration of aldehydes. Wiley-VCH Verlag GmbH & Co. KGaA, 2009.