113832-57-8Relevant articles and documents
Synthesis of (1-14C)butyl, (13C2-dimethyl) butyl and (2H6-dimethyl)butyl-neotame
Winwick, Thomas,Barnes, Roger D.
, p. 498 - 499 (2007)
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Efficient stereochemical relay en route to leucascandrolide A.
Kozmin
, p. 755 - 758 (2001)
[structure: see text]. A complete relay of the initial stereochemical information is central to the efficient and highly stereocontrolled construction of the C1-C15 fragment of the marine macrolide leucascandrolide A. Cyclic silane 3, assembled via Pt-cat
Synthesis of imines from amines in aliphatic alcohols on Pd/ZrO2 catalyst under ambient conditions
Cui, Wenjing,Zhaorigetu, Bao,Jia, Meilin,Ao, Wulan,Zhu, Huaiyong
, p. 2601 - 2604 (2014/01/06)
Synthesis of imines from amines and aliphatic alcohols (C 1-C6) in the presence of base on supported palladium nanoparticles has been achieved for the first time. The catalytic system shows high activity and selectivity in open air at room temperature.
PNP pincer osmium polyhydrides for catalytic dehydrogenation of primary alcohols
Bertoli, Marcello,Choualeb, Aldjia,Gusev, Dmitry G.,Lough, Alan J.,Major, Quinn,Moore, Brandon
body text, p. 8941 - 8949 (2011/10/12)
This paper reports the synthesis, structure, and properties of a series of PNP pincer complexes of osmium OsH3Cl[HN(C2H 4PiPr2)2] (1), OsH 3[N(C2H4PiPr2) 2] (2), OsH4[HN(C2H4P iPr2)2] (3), and OsH2(PMe 3)[HN(C2H4PiPr2) 2] (4). The tetrahydride 3 operates as an efficient catalyst at 0.1 mol% loading for the reactions of amination and dehydrogenative coupling of primary alcohols, producing secondary amines and symmetrical esters, respectively. The catalyst 3 is distinguished by outstanding stability, and it can be used in an aqueous environment at temperatures as high as 200 °C. The Royal Society of Chemistry 2011.
