65899-13-0Relevant academic research and scientific papers
Palladium- and copper-catalyzed 1,4-additions of organozinc compounds to conjugated aldehydes
Marshall, James A.,Herold, Martin,Eidam, Hilary S.,Eidam, Patrick
, p. 5505 - 5508 (2007/10/03)
Conjugated aldehydes undergo smooth Pd(OAc)2·PPh 3- or Me2CuCNLi2-catalyzed 1,4-addition of dialkylzinc reagents.
Studies related to fatty acid desaturation. Part I: Preparation of methyl-substituted nonanols, nonyl bromides and total synthesis of new branched oleic acids
Genard, S.,Patin, H.
, p. 397 - 406 (2007/10/02)
Convenient pathways for the synthesis of seven structurally defined isomers of methyl-nonanols and methyl-nonylbromides are described.These synthons are used to perform Wittig reactions between convenient phosphoranes and aldehydes in order to obtain seven new octadecenoic acids bearing a methyl grouping on carbons 11 to 17. branched nonan-1-ols / branched 1-nonylbromides / Wittig reactions / methyl 9-bromononanoate / methyl 8-formyloctanoate / methyl 11 or 17-methyloctadec-9-enoates
Catalytic Oxidation of Alk-1-enes to Aldehydes
Feringa, Ben L.
, p. 909 - 910 (2007/10/02)
Aldehydes are the major products of the catalytic oxidation of alk-1-enes with air using a catalyst that comprises (MeCN)2PdClNO2, CuCl2, and a tertiary alcohol.
