113881-89-3Relevant academic research and scientific papers
Studies Dealing with the Alkylation--Rearrangement Reaction of Some Phenylthio-Substituted Allylic Sulfones
Padwa, Albert,Bullock, William H.,Dyszlewski, Andrew D.
, p. 955 - 964 (2007/10/02)
A series of 2-(phenylthio)-3-(phenylsulfonyl)alkenes are easily metalated with n-butyllithium, and the resulting carbanion is regioselectively alkylated by alkyl halides in the α-position to give β,γ-unsaturated sulfones in high yield.These substituted ph
ALLYLIC 1,3-REARRANGEMENT OF THIOPHENYL SUBSTITUTED SULFONES
Padwa, Albert,Bullock, William H.,Dyszlewski, Andrew D.
, p. 3193 - 3196 (2007/10/02)
Substituted thiophenyl allyl sulfones undergo a 1,3-allylic sulfonyl shift and this rearrangement has been utilized within a metallation-alkylation sequence.
