1138816-10-0

Basic information

• Product Name: (ortho-Me-Ph)SnMe₂Cl
• Synonyms: (ortho-Me-Ph)SnMe₂Cl
• CAS NO: 1138816-10-0
• Molecular Weight: 275.365
• Mol File: 1138816-10-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (ortho-Me-Ph)SnMe₂Cl(CAS DataBase Reference)
• NIST Chemistry Reference: (ortho-Me-Ph)SnMe₂Cl(1138816-10-0)
• EPA Substance Registry System: (ortho-Me-Ph)SnMe₂Cl(1138816-10-0)

Safety Data

• Hazardous Substances Data: 1138816-10-0(Hazardous Substances Data)

Upstream product

• 7787-60-2 bismuth(III) chloride 
• 17113-82-5 1-methyl-2-(trimethylstannyl)benzene 

Relevant articles and documents

A sterically congested aryltrimethylstannane - Synthesis, reactivity, transmetalation and CH-π interaction

The synthesis of a novel sterically congested tetraorganotin compound, (4-tert-butyl-2,6-dimesitylphenyl)trimethylstannane (1), is reported and its reactivity with special focus on transmetalation studied. The reaction of compound 1 with reagents such as HgCl2, BiCl3 and HOTf gave (4-tert-butyl-2,6-dimesitylphenyl)dimethyltin chloride (2) and (4-tert-butyl-2,6-dimesitylphenyl)dimethyltin triflate (3), respectively, as a result of selective tin-methyl bond cleavage. Less bulky aryltrimethyltin derivatives react with BiCl3 to give both tin-methyl and tin-aryl bond cleavage. Hydrolysis of compound 3 proceeds slowly to give bis-(4-tert-butyl-2,6-dimesitylphenyl)dimethyl stannoxane (5) via the intermediate (4-tert-butyl-2,6-dimesitylphenyl)dimethyltin hydroxide (4). All terphenyldimethyltin derivatives that were characterized by single crystal X-ray diffraction analysis show C-H?π interactions. Based on these results, the optimum C-H?π distance (C?centroidaryl distance) is suggested to be in the range 3.4 and 3.5 A?.