113882-75-0Relevant articles and documents
MANUFACTURING METHOD OF ALKENYL PHOSPHORUS COMPOUND
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Paragraph 0045; 0046, (2019/10/01)
PROBLEM TO BE SOLVED: To provide a general synthesis method capable of providing various alkenyl phosphorus compound and a derivative thereof using a raw material which is easily available and easily handled without using a catalyst. SOLUTION: An alkenyl
Epoxysilanes as substrates in regio- and stereo-specific synthesis of silylated γ-hydroxyphosphane oxides, precursors of stereodefined allylphosphane oxides
González-Nogal, Ana M.,Cuadrado, Purificación
, p. 8080 - 8087 (2013/08/23)
Epoxysilanes experienced trans stereospecific α- or β-cleavage by the lithium derivative of methyldiphenylphosphane oxide leading to different compounds. The behaviour of the epoxysilanes towards this nucleophilic reagent depends on the nature of the sily