57415-92-6Relevant academic research and scientific papers
Primary Alcohols via Nickel Pentacarboxycyclopentadienyl Diamide Catalyzed Hydrosilylation of Terminal Epoxides
Lambert, Tristan H.,Steiniger, Keri A.
supporting information, p. 8013 - 8017 (2021/10/25)
The efficient and regioselective hydrosilylation of epoxides co-catalyzed by a pentacarboxycyclopentadienyl (PCCP) diamide nickel complex and Lewis acid is reported. This method allows for the reductive opening of terminal, monosubstituted epoxides to form unbranched, primary alcohols. A range of substrates including both terminal and nonterminal epoxides are shown to work, and a mechanistic rationale is provided. This work represents the first use of a PCCP derivative as a ligand for transition-metal catalysis.
Epoxysilanes as substrates in regio- and stereo-specific synthesis of silylated γ-hydroxyphosphane oxides, precursors of stereodefined allylphosphane oxides
González-Nogal, Ana M.,Cuadrado, Purificación
, p. 8080 - 8087 (2013/08/23)
Epoxysilanes experienced trans stereospecific α- or β-cleavage by the lithium derivative of methyldiphenylphosphane oxide leading to different compounds. The behaviour of the epoxysilanes towards this nucleophilic reagent depends on the nature of the sily
Phenylthioallyl and Phenylthiovinyl Phosphine Oxides: Synthesis of 1-Phenylthiobutadienes and a Three-component Synthesis of Ketones
Grayson, J. Ian,Warren, Stuart,Zaslona, Alex T.
, p. 967 - 976 (2007/10/02)
The functionalisation of some substituted allyl and vinyl diphenylphosphine oxides is explored and routes to substituted γ-phenylthioallyl and γ-phenylthiovinyl phosphine oxides are described.These reagents are used in the synthesis of the title compounds.
