113889-68-2

Upstream product

• 37699-03-9 (2',3',5'-tri-O-benzyl-β-D-ribofuranosyl)methyl alcohol 
• 100-39-0 benzyl bromide 
• 37699-02-8 2,5-anhydro-3,4,6-tri-O-benzyl-aldehydo-D-altrohexofuranose 
• 160701-96-2 2,5-anhydro-3,4,6-tri-O-benzyl-D-altrohexofuranose 
• 51450-29-4 2,3,5-tri-O-benzyl-1-O-(p-nitrobenzoyl)-β-D-ribofuranose 
• 84471-54-5 (2R,3R,4R,5S)-3,4-Bis-benzyloxy-2-benzyloxymethyl-5-bromo-tetrahydro-furan 
• 113794-40-4 1-(1-phenyl-2(Z)-ethylene)-2,3,5-tri-O-benzyl-β-D-ribose 
• 113794-41-5 1-(3-methoxy-1'(Z)-propenyl)-2,3,5-tri-O-benzyl-β-D-ribose 
• 113889-66-0 1-(2',3',5'-tri-O-benzyl-β-D-ribofuranosyl)-2-phenylacetylene 
• 113889-67-1 3-Methoxy-1-(2',3',5'-tri-O-benzyl-β-D-ribofuranosyl)-propin 

Relevant academic research and scientific papers

Selectivity in the SmI2-induced deoxygenation of thiazolylketoses for formyl C-glycoside synthesis and revised structure of C-ribofuranosides

Deoxygenation of thiazolylketose acetates using SmI2-(CH2OH)2 or TMSOTf-Et3SiH affords thiazolyl C-glycosides with opposite α/β ratios. Examination of the thiazolyl α- and β-C-ribofuranoside pair by NOE experime

Alkynylation of Mixed Acetals with Organotin Acetylides

Reaction of halo acetals containing O, N, or S heteroatoms with tri-n-butyltin acetylides in the presence of ZnCl2 in CCl4 leads to the formation of α-alkynyl ethers, amines, and sulfides in good yields.The methodology is exemplified with the synthesis of amino acids and C-glycosides.