113939-50-7Relevant articles and documents
N-PERHALOFLUOROALKYLATION OF SECONDARY AMINES BY THE REACTIONS OF THE AMINES AND AMIDES WITH PERHALOFLUOROALKANES. HALOPHILIC ATTACK OF NITROGEN NUCLEOPHILE ON C-Br BOND.
Li, Xing-ya,Pan, He-qi,Jiang, Xi-kui
, p. 3699 - 3702 (1987)
Secondary amines and amides react spontaneously with perhalofluoroalkanes CF2BrCFBrX(X = F, Cl, CF3) to afford N-perhalofluoroalkylated tertiary amines in fair to good yields.Evidence for an anionic chain process initiated by the bromophilic attack of nitrogen nucleophiles on C-Br bonds is given.