1139705-32-0Relevant academic research and scientific papers
Warming Up to Oxazole: Noncryogenic Oxazole Metalation and Negishi Coupling Development
Calimsiz, Selcuk,Geier, Michael J.,Humphreys, Luke D.,Scott, Mark E.,Wang, Xiaotian
, p. 1776 - 1781 (2019/09/09)
This report details the development of several suitable noncryogenic metalation conditions for the synthesis of oxazole zincate. Subsequent rounds of high-throughput catalyst screening ultimately led to the identification of several suitable Pd sources th
Regioselective functionalization of the oxazole scaffold using TMP-bases of Mg and Zn
Haas, Diana,Mosrin, Marc,Knochel, Paul
supporting information, p. 6162 - 6165 (2014/01/17)
A general method for the synthesis of 2,4,5-trisubstituted oxazoles has been developed. Starting from commercially available oxazole, successive metalations using TMPMgCl·LiCl or TMPZnCl·LiCl led to the corresponding magnesiated or zincated species which
Imidazolylsulfonates: Electrophilic partners in cross-coupling reactions
Albaneze-Walker, Jennifer,Raju, Ravinder,Vance, Jennifer A.,Goodman, Andrew J.,Reeder, Michael R.,Liao, Jing,Maust, Mathew T.,Irish, Patrick A.,Espino, Peter,Andrews, David R.
supporting information; experimental part, p. 1463 - 1466 (2009/08/07)
Aryl imidazolylsulfonates participate as electrophilic coupling partners in palladium-mediated cross-coupling reactions. The aryl imidazolylsulfonates display good stability while maintaining good reactivity in a variety of palladium-catalyzed coupling reactions. Imidazolylsulfonates are a practical and economic alternative to triflates.
