113989-39-2Relevant academic research and scientific papers
Chemistry and crystal structure of Cl containing a tridentate ylide ligand
Fontaine, Xavier L.R.,Herring, Andrew M.,Markham, David P.,Shaw, Bernard L.,Thornton-Pett, Mark
, p. 699 - 709 (1990)
Treatment of cis- with Me2NNH2 in hot benzene gives the title compound (1a) in high yield.Similar treatment of , X = Br or I, gives the corresponding bromo- or iodo-complexes X, X = Br or I. 1a with NH4PF6 gives the corresponding PF6 salt , which with dilute HCl and NH4PF6 gives 2.Treatment of 1a with NaBH4 gives a neutral hydrido complex, formulated as .The crystal structure of 1a has been determined.NMR data are given.
Formation and Crystal Structure of NMe2NHCH2CHPPh2CH2CH2PPh2>Cl containing a Novel Tridentate Ylide Ligand formed by Intramolecular Phosphinovinylation
Herring, Andrew M.,Markham, David P.,Shaw, Bernard L.,Thornton-Pett, Mark
, p. 643 - 644 (2007/10/02)
Treatment of cis- with Me2NNH2 gives the title compound, formed by successive conjugate addition to the vinyl groups, including attack by one P-atom on a vinyl group of an adjacent co-ordinated PPh2CH=CH2 ligand; some reactions of the
