114091-85-9

Basic information

• Product Name: Cyclohexaneacetic acid, a-bromo-1-hydroxy-, ethyl ester
• CAS NO: 114091-85-9
• Molecular Formula: C10H17BrO3
• Molecular Weight: 265.147
• Mol File: 114091-85-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Cyclohexaneacetic acid, a-bromo-1-hydroxy-, ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexaneacetic acid, a-bromo-1-hydroxy-, ethyl ester(114091-85-9)
• EPA Substance Registry System: Cyclohexaneacetic acid, a-bromo-1-hydroxy-, ethyl ester(114091-85-9)

Safety Data

• Hazardous Substances Data: 114091-85-9(Hazardous Substances Data)

Upstream product

• 617-33-4 ethyl dibromoacetate 
• 108-94-1 cyclohexanone 
• 120-92-3 cyclopentanone 

Downstream Products

• 6975-17-3 ethyl 1-oxaspiro[2.5]octane-2-carboxylate 

Relevant articles and documents

An efficient synthesis of 2-bromo-3-hydroxy esters by reaction of ketones with ethyl dibromoacetate promoted by samarium diiodide

A simple and efficient samarium diiodide mediated synthesis of 2-bromo-3-hydroxy esters 1 by the reaction of a variety of ketones 2 with ethyl dibromoacetate (3) is described. The relative configuration of the major diastereoisomer obtained was established by NOESY experiments of the corresponding α,β-epoxy esters 4 prepared from 1. Additionally, a mechanism is proposed to explain the results obtained. Wiley-VCH Verlag GmbH & Co. KGaA, 2006.