1141365-40-3Relevant academic research and scientific papers
Catalytic asymmetric synthesis of (+)-anthecotulide using enyne and Meyer-Schuster rearrangements
Hodgson, David M.,Talbot, Eric P. A.,Clark, Barry P.
supporting information; experimental part, p. 5751 - 5753 (2011/12/05)
The bioactive sesquiterpene lactone (+)-anthecotulide (1) is synthesized for the first time, in a six-step sequence devoid of protecting groups. The key transformations are a novel Rh(I)-catalyzed asymmetric enyne rearrangement of a terminal alkynyl ester
Synthesis of (-)-berkelic acid
Wu, Xiaoxing,Zhou, Jingye,Snider, Barry B.
supporting information; experimental part, p. 1283 - 1286 (2009/06/30)
An extremophilic challenge: Stereospecific condensation of a fully functionalized ketal aldehyde and a 2,6-dihydroxybenzoic acid is the key step in the synthesis of (-)-berkelic acid confirming Fuerstner's reassignment of the stereochemistry at C18 and C1
