114137-92-7

Upstream product

• 114114-44-2 (R)-2-[(4S,5S,6R)-6-[(1R,2R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-butyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-propan-1-ol 
• 882-33-7 diphenyldisulfane 
• 114114-36-2 (2R,3S,4R)-2-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-4-[1,3]dithian-2-yl-pentan-3-ol 
• 114130-12-0 (S)-4-[(1R,2S,3R)-3-[1,3]Dithian-2-yl-2-(4-methoxy-benzyloxy)-1-methyl-butyl]-2,2-dimethyl-[1,3]dioxolane 
• 114114-44-2 (R)-2-[(2R,4S,5S,6R)-6-[(1R,2R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-butyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-propan-1-ol 
• 114114-42-0 (3S,4R,5S,6R,7R,8R)-8-(tert-Butyl-diphenyl-silanyloxy)-4-hydroxy-6-(4-methoxy-benzyloxy)-3,5,7-trimethyl-1,1,1-triphenyl-decan-2-one 
• 129269-46-1 Toluene-4-sulfonic acid (2S,3S,4S,5R)-5-[1,3]dithian-2-yl-2-hydroxy-4-(4-methoxy-benzyloxy)-3-methyl-hexyl ester 
• 114114-38-4 (S)-2-[(1R,2S,3R)-3-[1,3]Dithian-2-yl-2-(4-methoxy-benzyloxy)-1-methyl-butyl]-oxirane 
• 142143-78-0 (2S,3R,4S,5R)-5-[1,3]Dithian-2-yl-3-methyl-hexane-1,2,4-triol 
• 114114-37-3 (2S,3S,4S,5R)-5-[1,3]Dithian-2-yl-4-(4-methoxy-benzyloxy)-3-methyl-hexane-1,2-diol 
• 114114-39-5 (3R,4S,5S,6R)-6-[1,3]Dithian-2-yl-5-(4-methoxy-benzyloxy)-4-methyl-heptan-3-ol 
• 114114-43-1 (S)-3-[(2S,4R,5R,6R)-6-[(1R,2R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-butyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-1,1,1-triphenyl-butan-2-one 
• 114114-40-8 tert-Butyl-[(1R,2R,3S,4R)-4-[1,3]dithian-2-yl-1-ethyl-3-(4-methoxy-benzyloxy)-2-methyl-pentyloxy]-diphenyl-silane 
• 114114-41-9 (2R,3S,4R,5R)-5-(tert-Butyl-diphenyl-silanyloxy)-3-(4-methoxy-benzyloxy)-2,4-dimethyl-heptanal 

Downstream Products

• 114114-45-3 {(1R,2R)-2-[(4R,5R,6R)-6-[(S)-2-((S)-Benzenesulfinyl)-1-methyl-ethyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-1-ethyl-propoxy}-tert-butyl-diphenyl-silane 
• 114114-45-3 {(1R,2R)-2-[(4R,5R,6R)-6-[(S)-2-((R)-Benzenesulfinyl)-1-methyl-ethyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-1-ethyl-propoxy}-tert-butyl-diphenyl-silane 
• 3225-82-9 Erythronolide B 
• 56014-68-7 3,5-O-benzylidene-(9S)-dihydroerythronolide B 
• 123107-83-5 3,5-O-benzylideneerythronolide B 
• 114137-94-9 3,5-isopropylidene-9-11-O-(p-methoxybenzylidene)-9(S)-dihydroerythronolide B 
• 123219-40-9 (2R,4R)-4-[(2R,4S,5S,6R)-6-[(1R,2R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-butyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-2-[(4R,5S,6R)-2,2,5-trimethyl-6-((S)-1-methyl-allyl)-[1,3]dioxan-4-yl]-pentan-2-ol 
• 123219-39-6 (2S,3R,4S)-4-[(2S,4R,5R,6R)-6-[(1R,2R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-butyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-3-phenylsulfanyl-2-[(4R,5S,6R)-2,2,5-trimethyl-6-((S)-1-methyl-allyl)-[1,3]dioxan-4-yl]-pentan-2-ol 
• 114114-45-3 {(1R,2R)-2-[(2S,4R,5R,6R)-6-[(S)-2-((R)-Benzenesulfinyl)-1-methyl-ethyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-1-ethyl-propoxy}-tert-butyl-diphenyl-silane 
• 114137-93-8 (2R,3R,4S)-3-Benzenesulfinyl-4-[(2S,4R,5R,6R)-6-[(1R,2R)-2-(tert-butyl-diphenyl-silanyloxy)-1-methyl-butyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-2-[(4R,5S,6R)-2,2,5-trimethyl-6-((S)-1-methyl-allyl)-[1,3]dioxan-4-yl]-pentan-2-ol 
• 114137-93-8 (2S,3R,4S)-3-Benzenesulfinyl-4-[(2S,4R,5R,6R)-6-[(1R,2R)-2-(tert-butyl-diphenyl-silanyloxy)-1-methyl-butyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-2-[(4R,5S,6R)-2,2,5-trimethyl-6-((S)-1-methyl-allyl)-[1,3]dioxan-4-yl]-pentan-2-ol 
• 114181-58-7 {(1R,2R)-2-[(2S,4R,5R,6R)-6-[(S)-2-((S)-Benzenesulfinyl)-1-methyl-ethyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-1-ethyl-propoxy}-tert-butyl-diphenyl-silane 
• 114137-93-8 (2S,3R,4S)-3-Benzenesulfinyl-4-[(4R,5R,6R)-6-[(1R,2R)-2-(tert-butyl-diphenyl-silanyloxy)-1-methyl-butyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-2-[(4R,5S,6R)-2,2,5-trimethyl-6-((S)-1-methyl-allyl)-[1,3]dioxan-4-yl]-pentan-2-ol 
• 114137-93-8 (2R,3R,4S)-3-Benzenesulfinyl-4-[(4R,5R,6R)-6-[(1R,2R)-2-(tert-butyl-diphenyl-silanyloxy)-1-methyl-butyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-2-[(4R,5S,6R)-2,2,5-trimethyl-6-((S)-1-methyl-allyl)-[1,3]dioxan-4-yl]-pentan-2-ol 

Relevant academic research and scientific papers

STEREO-CONTROLLED SYNTHESIS OF ERYTHRONOLIDES A AND B FROM 1,6-ANHYDRO-β-D-GLUCOPYRANOSE (LEVOGLUCOSAN). SKELETON ASSEMBLY IN (C9 - C13) + (C7 - C8) + (C1 - C6) SEQUENCE

Stereospecific syntheses of erythronolides A and B have been accomplished starting from 1,6-anhydro-β-D-glucopyranose (levoglucosan) in a uniform synthetic sequence.

TOTAL SYNTHESIS OF ERYTHRONOLIDE B. 1. SKELETON ASSEMBLY IN (C9-C13) + (C7-C8) + (C1-C6) SEQUENCE.

Erythronolide B has been synthesized starting from levoglucosan.