1141682-89-4Relevant academic research and scientific papers
Diastero- and enantioselective intramolecular carbometalation reaction
Unger, Rozalia,Cohen, Theodore,Marek, Ilan
, p. 4874 - 4881 (2010)
The zinc-catalyzed addition of various alkynes to acylsilanes followed by a Zn-Brook rearrangement and either the Zn-ene-allene or Zn-yne-allene cyclization led to the enantio- and diastereoselective formation of carbocycles in a single-pot operation.
Enantio- and diastereoselective tandem zn-promoted brook rearrangement/ene - Allene carbocyclization reaction
Linger, Rozalia,Weisser, Fritz,Chinkov, Nicka,Stanger, Amnon,Cohen, Theodore,Marek, Han
supporting information; experimental part, p. 1852 - 1855 (2009/09/25)
The zinc-catalyzed addition of various alkynes to acylsilanes followed by a Zn- Brook rearrangement and either the Zn- ene- allene or Zn- yne- allene cyclization led to the enantio- and diastereoselective formation of carbocycles in a single-pot operation
