Diastero- and enantioselective intramolecular carbometalation reaction

DOI: 10.1016/j.tet.2010.04.038

Source and publish data:

Tetrahedron p. 4874 - 4881 (2010)

Update date:2022-07-30

Topics:

Authors:

Unger, Rozalia

Cohen, Theodore

Marek, Ilan

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Article abstract of DOI:10.1016/j.tet.2010.04.038

The zinc-catalyzed addition of various alkynes to acylsilanes followed by a Zn-Brook rearrangement and either the Zn-ene-allene or Zn-yne-allene cyclization led to the enantio- and diastereoselective formation of carbocycles in a single-pot operation.

Full text of DOI:10.1016/j.tet.2010.04.038

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