114181-54-3

Basic information

• Product Name: (3R,4R,5R,7R)-5-Benzyloxy-8-(tert-butyl-dimethyl-silanyloxy)-3,5,7-trimethyl-oct-1-en-4-ol
• Synonyms: (3R,4R,5R,7R)-5-Benzyloxy-8-(tert-butyl-dimethyl-silanyloxy)-3,5,7-trimethyl-oct-1-en-4-ol
• CAS NO: 114181-54-3
• Molecular Weight: 406.681
• Mol File: 114181-54-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (3R,4R,5R,7R)-5-Benzyloxy-8-(tert-butyl-dimethyl-silanyloxy)-3,5,7-trimethyl-oct-1-en-4-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (3R,4R,5R,7R)-5-Benzyloxy-8-(tert-butyl-dimethyl-silanyloxy)-3,5,7-trimethyl-oct-1-en-4-ol(114181-54-3)
• EPA Substance Registry System: (3R,4R,5R,7R)-5-Benzyloxy-8-(tert-butyl-dimethyl-silanyloxy)-3,5,7-trimethyl-oct-1-en-4-ol(114181-54-3)

Safety Data

• Hazardous Substances Data: 114181-54-3(Hazardous Substances Data)

Upstream product

• 31197-41-8 crotyltributylstannane 
• 114114-18-0 (2R,4R)-2-benzyloxy-5-tert-butyldimethylsiloxy-2,4-dimethylpentanal 
• 35998-93-7 tri-n-butylcrotyltin 
• 134744-29-9 (2S,3R,5R)-3-Benzyloxy-2-bromomethyl-6-methoxy-3,5-dimethyl-tetrahydro-pyran 
• 134744-28-8 ((2R,3R,5R)-3-Benzyloxy-6-methoxy-3,5-dimethyl-tetrahydro-pyran-2-yl)-methanol 
• 134744-30-2 (2R,4R)-4-Benzyloxy-2,4-dimethyl-hex-5-en-1-ol 
• 100-39-0 benzyl bromide 
• 123518-87-6 1,6-anhydro-2-desoxy-2,4-di-C-methyl-3-O-(4-methoxybenzyl)-4-O-benzyl-β-D-galactopyranose 
• 114114-17-9 (3R,5R)-3-benzyloxy-6-tert-butyldimethylsiloxy-3,5-dimethylhex-1-ene 
• 123493-66-3 1,6-anhydro-2-desoxy-2,4-di-C-methyl-3-O-(4-methoxybenzyl)-β-D-galactopyranose 
• 81076-78-0 1,6-anhydro-2-desoxy-2,4-di-C-methyl-4-O-benzyl-β-D-galactopyranose 
• 123493-62-9 1,6-anhydro-2,3-didesoxy-2,4-di-C-methyl-4-O-benzyl-β-D-galactopyranose 
• 114114-16-8 (2R,4R)-4-Benzyloxy-2,4-dimethyl-hex-5-enal 

Downstream Products

• 114181-57-6 (2R,3R,5R,6R)-3-Benzyloxy-6-methoxy-3,5-dimethyl-2-((R)-1-methyl-allyl)-tetrahydro-pyran 
• 123493-57-2 (2R,4R,5R,6R)-4-Benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-2,4,6-trimethyl-oct-7-en-1-ol 
• 123493-59-4 {(2R,4R)-4-Benzyloxy-4-[(4R,5R)-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-2-methyl-pentyloxy}-tert-butyl-dimethyl-silane 
• 134744-46-0 (2R,3R,4R,6R)-4-Benzyloxy-7-(tert-butyl-dimethyl-silanyloxy)-3-(4-methoxy-benzyloxy)-2,4,6-trimethyl-heptan-1-ol 
• 123493-58-3 (2S,3R,4R,6R)-4-Benzyloxy-7-(tert-butyl-dimethyl-silanyloxy)-3-(4-methoxy-benzyloxy)-2,4,6-trimethyl-heptanal 
• 123539-40-2 (2R,3R,5R,6S)-3-Benzyloxy-6-methoxy-3,5-dimethyl-2-((R)-1-methyl-allyl)-tetrahydro-pyran 
• 123539-38-8 [(2R,4R,5R,6R)-4-Benzyloxy-5-(4-methoxy-benzyloxy)-2,4,6-trimethyl-oct-7-enyloxy]-tert-butyl-dimethyl-silane 

Relevant articles and documents

Stereocontrolled synthesis of erythronolides A and B in a (C5-C9) + (C3-C4) + (C1-C2) + (C11-C13) sequence from 1,6-anhydro-β-D-glycopyranose (levoglucosan). Part 1. Synthesis of C1-C10 and C11-C13 segments

An approach to the synthesis of aglycones of macrolide antibiotics erythromycin A and B is discussed and preparation of common C1-C10 and C11-C13 segments starting from levoglucosane is described.

TOTAL SYNTHESIS OF ERYTHRONOLIDE B. 2. SKELETON ASSEMBLY IN (C5-C9) + (C3-C4) + (C1-C2) + (C11-C13) SEQUENCE.

Erythronolide B has been synthesized starting from levoglucosan.