114191-22-9

Upstream product

• 824-94-2 p-methoxybenzyl chloride 
• 114191-21-8 S-(2S,3E)-2-Ethoxycarbonylpent-3-en-2-yl S-methyldithiocarbonate 
• 188443-77-8 (S,E)-ethyl 4-(tert-butyldimethylsilyloxy)-2-methylpent-2-enoate 
• 114191-19-4 (4S,2E)-ethyl 4-hydroxy-2-methylpent-2-enoate 
• 114191-20-7 O-(2S,3E)-4-Ethoxycarbonylpent-3-en-2-yl S-methyldithiocarbonate 

Downstream Products

• 123401-97-8 2-(4-methoxy-phenylmethanesulfanyl)-propionic acid ethyl ester 
• 123401-98-9 Ethyl (2S,3E)-2,4-dimethyl-2-(4-methoxybenzylthio)hexa-3,5-dienoate 
• 123401-96-7 Ethyl (2S,3E)-4-formyl-2-(4-methoxybenzylthio)-2-methylpent-3-enoate 
• 123430-68-2 Ethyl (2S,3E)-2,4-dimethyl-6-hydroxy-2-(4-methoxybenzylthio)hex-3-enoate 
• 114191-26-3 Ethyl (4S,5E)-4-(4-methoxybenzylthio)-4-methyl-3-oxohept-5-enoate 
• 188443-95-0 (2S,3E)-6-(4-Chlorophenylselenenyl)-2,4-dimethyl-2-(4-methoxybenzylthio)hex-3-enoic acid 
• 123430-69-3 Ethyl (2S,3E)-6-(4-chlorophenylseleno)-2,4-dimethyl-2-(4-methoxybenzylthio)hex-3-enoate 
• 123401-99-0 1-<(2S,3E)-6-(4-Chlorophenylselenenyl)-2,4-dimethyl-2-(4-methoxybenzylthio)hex-3-enoyl>imidazole 
• 188444-26-0 Methyl (4S,5E)-8-(4-chlorophenylselenenyl)-4-(4-methoxybenzylthio)-2,4,6-trimethyl-3-oxooct-5-enoate 
• 188444-04-4 (E)-(S)-4-(4-Methoxy-benzylsulfanyl)-2,4,6-trimethyl-3-oxo-7-(2-trimethylsilanyl-ethoxymethoxy)-hept-5-enoic acid methyl ester 
• 188444-00-0 (E)-(S)-1-Imidazol-1-yl-2-(4-methoxy-benzylsulfanyl)-2,4-dimethyl-5-(2-trimethylsilanyl-ethoxymethoxy)-pent-3-en-1-one 
• 188443-98-3 (S)-1-Imidazol-1-yl-2-(4-methoxy-benzylsulfanyl)-2-methyl-3-(2-trimethylsilanyl-ethoxymethoxy)-propan-1-one 
• 188444-03-3 (S)-4-(4-Methoxy-benzylsulfanyl)-5-(2-methoxy-ethoxymethoxy)-2,4-dimethyl-3-oxo-pentanoic acid methyl ester 
• 188443-93-8 (E)-(S)-2-(4-Methoxy-benzylsulfanyl)-2,4-dimethyl-5-(2-trimethylsilanyl-ethoxymethoxy)-pent-3-enoic acid ethyl ester 

Relevant academic research and scientific papers

Asymmetric synthesis of 5,5-disubstituted thiotetronic acids using an allyl xanthate to dithiocarbonate rearrangement: Total synthesis of (55)-thiolactomycin with revision of the absolute configuration of the natural product

An asymmetric synthesis of thiotetronic acids related to the antibiotics thiolactomycin 1 and thiotetromycin 2 has been developed in which the key step is a stereoselective [3.3]-rearrangement of an allyl xanthate to the corresponding dithiocarbonate. Thu

An Asymmetric Synthesis of Thiotetronic Acids using Chirality Transfer via an Allyl Xanthate-to-Dithiocarbonate Rearrangement. X-Ray Crystal Structure of (5R)-2,5-Dihydro-4-hydroxy-5-methyl-3-phenyl-5-prop-1'-enyl-2-oxothiophene

An asymmetric synthesis of thiotetronic acids has been developed which is based upon an allyl xanthate-to-dithiocarbonate rearrangement, the absolute configuration of the products being confirmed by an X-ray crystal structure determination.