188474-82-0

Upstream product

• 824-94-2 p-methoxybenzyl chloride 
• 188443-83-6 Ethyl (2R,3E)-2-(4-methoxybenzylthio)-2-methylpent-3-enoate 
• 188443-87-0 (2R,3E)-2-(4-Methoxybenzylthio)-2-methylpent-3-enoic acid 
• 114191-31-0 S-(2R,3E)-2-Ethoxycarbonylpent-3-en-2-yl S-methyldithiocarbonate 
• 188443-81-4 O-(2R,3E)-4-Ethoxycarbonylpent-3-en-2-yl S-methyldithiocarbonate 
• 114191-30-9 Ethyl (2E,4R)-4-hydroxy-2-methylpent-2-enoate 
• 114191-19-4 (4S,2E)-ethyl 4-hydroxy-2-methylpent-2-enoate 
• 554-12-1 propanoic acid methyl ester 
• 188443-96-1 1-<(2R,3E)-2-(4-Methoxybenzylthio)-2-methylpent-3-enoyl>imidazole 
• 188443-77-8 (S,E)-ethyl 4-(tert-butyldimethylsilyloxy)-2-methylpent-2-enoate 
• 188443-86-9 (2S,3E)-2-(4-Methoxybenzylthio)-2-methylpent-3-enoic acid 
• 114191-21-8 S-(2S,3E)-2-Ethoxycarbonylpent-3-en-2-yl S-methyldithiocarbonate 
• 114191-20-7 O-(2S,3E)-4-Ethoxycarbonylpent-3-en-2-yl S-methyldithiocarbonate 
• 114191-22-9 Ethyl (2S,3E)-2-(4-methoxybenzylthio)-2-methylpent-3-enoate 

Relevant academic research and scientific papers

Asymmetric synthesis of 5,5-disubstituted thiotetronic acids using an allyl xanthate to dithiocarbonate rearrangement: Total synthesis of (55)-thiolactomycin with revision of the absolute configuration of the natural product

An asymmetric synthesis of thiotetronic acids related to the antibiotics thiolactomycin 1 and thiotetromycin 2 has been developed in which the key step is a stereoselective [3.3]-rearrangement of an allyl xanthate to the corresponding dithiocarbonate. Thu

An Asymmetric Synthesis of Thiotetronic Acids using Chirality Transfer via an Allyl Xanthate-to-Dithiocarbonate Rearrangement. X-Ray Crystal Structure of (5R)-2,5-Dihydro-4-hydroxy-5-methyl-3-phenyl-5-prop-1'-enyl-2-oxothiophene

An asymmetric synthesis of thiotetronic acids has been developed which is based upon an allyl xanthate-to-dithiocarbonate rearrangement, the absolute configuration of the products being confirmed by an X-ray crystal structure determination.