114262-54-3Relevant academic research and scientific papers
ON THE STEREOSELECTIVITY OF REACTIONS BETWEEN Α-METHYLBUT-2-ENYLSTANNANES AND ALDEHYDES.
Hull, Caroline,Mortlock, Simon V.,Thomas, Eric J.
, p. 1007 - 1016 (2007/10/02)
α-Methylbut-2-enylstannanes (7) - (9) react stereoselectively on heating with aldehydes to form anti-5-hydroxy-4-methyl-Z-pent-2-enes (16) and (17).In the presence of BF3*Et2O, the major products are the corresponding syn-5-hydroxy-4-methyl-E-pent-2-enes
Stereoselective Synthesis of Z-Alkenes from α-Methylcrotylstannanes and Aldehydes
Hull, Caroline,Mortlock, Simon V.,Thomas, Eric J.
, p. 5343 - 5346 (2007/10/02)
α-Methylcrotylstannanes (6)-(8) and aldehydes react stereoselectively on heating to give anti-5-hydroxy-4-methyl-Z-pent-2-enes (9) and (10).
