114342-67-5

Upstream product

• 104826-13-3 1D-4,5-di-O-allyl-3,6-di-O-benzyl-1-l-menthoxyacetyl-myo-inositol 
• 104873-74-7 1D-1,4,5-tri-O-allyl-3,6-di-O-benzyl-myo-inositol 
• 104826-12-2 (+/-)-4,5-di-O-allyl-3,6-di-O-benzyl-1,2-O-cyclohexylidene-myo-inositol 
• 98925-52-1 (+/-)-5,6-di-O-allyl-1,4-di-O-benzyl-myo-inositol 
• 104873-73-6 1L-5,6-di-O-allyl-1,4-di-O-benzyl-myo-inositol 
• 100-44-7 benzyl chloride 
• 23486-92-2 3,6-di-O-benzyl-1,2:4,5-di-O-cyclohexylidene-D(L)-myo-inositol 
• 35949-66-7 (+/-)-1,4-di-O-benzyl-2,3-O-cyclohexylidene-myo-inositol 
• 34361-60-9 1,2:4,5-dicyclohexylidene-myo-inositol 
• 6763-47-9 rac-1,2-O-cyclohexylidene-myo-inositol 
• 87-89-8 D-myo-inositol 
• 104873-75-8 (-)-1D-1,4,5-tris-O-allyl-2,3,6-tris-O-benzyl-myo-inositol 

Downstream Products

• 104826-14-4 1L-1,2,4-tri-O-benzyl-3,5,6-tris-O-dianilinophosphoryl-myo-inositol 
• 116907-55-2 1L-1,2,4-tri-O-benzyl-3,5,6-tris-O-dibenzyloxyphosphoryl-myo-inositol 
• 141611-64-5 1L-1,2,4-tri-O-benzyl-3,5,6-tris-O-(o-xylylenedioxyphosphoryl)-myo-inositol 
• 104873-76-9 2,3,6-tris-O-(phenylmethyl)-D-myo-inositol 

Relevant academic research and scientific papers

Synthesis and Some Properties of D-myo-Inositol 1,4,5-Tris(dihydrogen phosphate)

Optically active myo-inositol 1,4,5-tris(dihydrogen phosphate) 1, which has now been recognized as a second messenger in a new intracellular signal transduction system, has been prepared starting from myo-inositol.The key step, phosphorylation of an adequately protected polyhydroxy derivative, was accomplished by three methods, among which a phosphoramidite method using a new phosphitylating agent, o-xylylene N,N-diethylphosphoramidite, gave the triphosphoric ester in quantitative yield.Optical resolution was effectively realized by derivatization into diastereoisomeric l-menthoxyacetic esters.NMR spectra and optical rotation are shown to depend on the pH of an aqueous solution of compound 1.