114367-42-9Relevant academic research and scientific papers
KOMPLEXCATALYSE. XXVII. ZUR ANIONENCOORDINATION IN η3-ALLYLBIS(TRIPHENYLPHOSPHIT)NICKEL(II)-KOMPLEXEN X (X=PF6, B(O2C6H4)2, BF4, AlBr4, CH3C6H4SO3, Cl, Br, I) UND DEREN EINFLUSS AUF DIE KATALYTISCHE AKTIVITAET DER KOMPLEXE FUER DIE STEREOSPECIFISCHE BUTADIENPOLYME...
Taube, Rudolf,Gehrke, Joerg-Peter
, p. 419 - 428 (1987)
Synthesis and characterisation of a series of η3-allylbis(triphenylphosphite)nickel(II) complexes X with the anions X- = PF6-, B(O2C6H4)2-, BF4-, AlBr4-, CH3CH4SO3-, Cl-, Br-, I- is described.Conductivity measurements and 13C NMR spectroscopy confirmed increasing coordination of the anion in the given series, which is accompanied by some inhibition, to a greater or lesser extent, of the catalytic activity of the complexes in stereospecific butadiene polymerization.
