1144111-27-2Relevant academic research and scientific papers
Stereoselective synthesis of highly substituted α-silylamines from silylmethyl azides under Ru catalysis
Jeong, Wook,Kim, Jungjoon,Park, Jaiwook,Rhee, Young Ho
, p. 7577 - 7581 (2014)
A synthetic strategy towards highly substituted α-silyl homoallylic amines was discovered. The key event is the unique synthesis of N-unsubstituted α-silylimines from azide precursors under mild conditions. Of particular note is the unprecedented access to α-silylamines possessing multiple stereocenters and functional groups with high diastereo-and enantioselectivity. The synthetic utility of the method was demonstrated by the use of the silyl moiety as the key element that enables late-stage modification for the iminium ion mediated oxidative cyclization.
Syntheses and crystal structures of azafulleroid and aziridinofullerene bearing silyl or germyl benzene
Hachiya, Houjin,Kakuta, Toshiyuki,Takami, Makoto,Kabe, Yoshio
experimental part, p. 630 - 636 (2009/05/30)
Addition of silyl and germylmethyl azides (1) to fullerene C60 at 50 °C through [2+3] cycloaddition led to the formation of the triazoline adducts (2). Subsequently, heating 2 at 100 °C in the solid state, caused N2 extrusion produci
