114467-03-7

Basic information

• Product Name: C₁₄H₁₃N₂O₅S*H⁽¹⁺⁾
• Synonyms: C₁₄H₁₃N₂O₅S*H⁽¹⁺⁾
• CAS NO: 114467-03-7
• Molecular Weight: 322.342
• Mol File: 114467-03-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₄H₁₃N₂O₅S*H⁽¹⁺⁾(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₄H₁₃N₂O₅S*H⁽¹⁺⁾(114467-03-7)
• EPA Substance Registry System: C₁₄H₁₃N₂O₅S*H⁽¹⁺⁾(114467-03-7)

Safety Data

• Hazardous Substances Data: 114467-03-7(Hazardous Substances Data)

Upstream product

• 6209-72-9 4-nitrobenzenesulfonyl peroxide 
• 104-84-7 para-methylbenzylamine 

Downstream Products

• 138-42-1 p-nitrobenzenesulfonic acid 
• 45708-98-3 C₈H₈N*H⁽¹⁺⁾ 

Relevant articles and documents

Structural Effects on the Transition States of Imine-Forming Eliminations in N-Substituted O-(Arylsulfonyl)hydroxylamines

A series of amines with various alkyl and aryl substituents at C-1 were converted to the corresponding N-(arylsulfonoxy)amines, which served as precursors for base-promoted, imine-forming elimination.By varying the bases used to promote the elimination and by varying the leaving groups attached to nitrogen, the Broensted parameters β and βlgCH3 were determined.These were used to locate the transition state on the More O'Ferrall-Jencks energy surface for elimination.Substituents were found to influence the structure of the activated complex markedly.Resonance effects were most important, while inductive effects had little influence .