114467-77-5

Basic information

• Product Name: (difluoro(4-nitrophenyl)methyl)(phenyl)sulfide
• Synonyms: (difluoro(4-nitrophenyl)methyl)(phenyl)sulfide
• CAS NO: 114467-77-5
• Molecular Weight: 281.283
• Mol File: 114467-77-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (difluoro(4-nitrophenyl)methyl)(phenyl)sulfide(CAS DataBase Reference)
• NIST Chemistry Reference: (difluoro(4-nitrophenyl)methyl)(phenyl)sulfide(114467-77-5)
• EPA Substance Registry System: (difluoro(4-nitrophenyl)methyl)(phenyl)sulfide(114467-77-5)

Safety Data

• Hazardous Substances Data: 114467-77-5(Hazardous Substances Data)

Upstream product

• 243656-25-9 2,2-difluoro-2-(4-nitrophenyl)acetic acid ethyl ester 
• 882-33-7 diphenyldisulfane 
• 29848-57-5 4-(difluoromethyl)nitrobenzene 
• 23837-16-3 ((4-nitrophenyl)methylene)bis(phenylsulfane) 
• 114467-74-2 1-(bromo-difluoro-methyl)-4-nitro-benzene 
• 3111-52-2 potassium thiophenolate 
• 555-16-8 4-nitrobenzaldehdye 

Relevant articles and documents

PRODUCTION METHOD OF DIFLUOROMETHYLENE COMPOUND

PROBLEM TO BE SOLVED: To provide a production method of a difluoromethylene compound. SOLUTION: The production method of a difluoromethylene compound represented by formula (IIIa) id provided in which difluoro acetate represented by formula (Ia) is reacted with an aryl electrophile represented by formula (IIa). In the formulas, R represents CN, NO2, C(O)OC2H5, COCH3 or Cl; m represents an integer of 1 or 2; M represents Li, Na, K, Rb or Cs; Ar represents a phenyl group or a phenylalkyl group, the alkyl portion having 1-5C, which may be optionally substituted by a substituent selected from the group consisting of a -Cl group, a -OCH3 group and a -C(O)OC2H5 group. COPYRIGHT: (C)2015,JPOandINPIT

Syntheses of New Aromatic Compounds with Fluorinated Side Chains and their Chemical Reactivity

The syntheses of a wide range of aromatic compounds of the type p-Y-C6H4CF2X(4-13) are described, and the chemical behavior of these compounds as a function of substituent Y is investigated .Analogously the pyridine derivatives 15, 17, and 18 were synthesized and characterized.From a correlation of the 19F-NMR data of these compounds with the Hammett constant of Y, participation of C-F ?-back-donation is seen as the cause for an observed shift of the 19F signals to lower field.