114493-69-5

Upstream product

• 100-39-0 benzyl bromide 
• 114473-54-0 C₂₁H₃₀O₆ 
• 114473-53-9 {(1R,2R,4S,5S,6S,7R)-7-[(4R,5R)-5-((1S,2S,4R,5R,6R,7S)-7-Hydroxymethyl-3-oxa-tricyclo[3.2.1.0^2,4]oct-6-yl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-3-oxa-tricyclo[3.2.1.0^2,4]oct-6-yl}-methanol 
• 114473-51-7 C₂₅H₃₄O₆ 

Downstream Products

• 114473-59-5 (1R,2R)-1,2-Bis-((1R,2R,3R,6S,7S,9R)-2-benzyloxy-4-oxa-tricyclo[4.2.1.0^3,7]non-9-yl)-ethane-1,2-diol 
• 114473-56-2 (1R,2R,3R,6S,7S,9R)-2-Benzyloxy-9-phenylsulfanylmethyl-4-oxa-tricyclo[4.2.1.0^3,7]nonane 
• 114473-55-1 ((1R,2R,3R,6R,7S,9R)-2-Benzyloxy-4-oxa-tricyclo[4.2.1.0^3,7]non-9-yl)-methanol 
• 114473-57-3 (1R,2R,3R,6R,7S,9R)-2-Benzyloxy-9-methyl-4-oxa-tricyclo[4.2.1.0^3,7]nonane 

Relevant academic research and scientific papers

A DOUBLE DIELS-ALDER REACTION OF A C2-SYMMETRIC BIS-DIENOPHILE: A NEW ENANTIOSELECTIVE APPROACH TO NATURAL LOGANIN

Reaction of a chiral C2-symmetric bis-dienophile 1 and cyclopentadiene gave a mixture (3:2) of adducts 2 and 3 of which the major one was converted into a key intermediate 12 of loganin.The formation of the adducts is presumed via the anti-Felkin-Anh type active conformers, 14 and 15, respectively.