1145681-60-2Relevant academic research and scientific papers
Anti-selective epoxidation of methyl α-methylene-β-tert- butyldimethylsilyloxycarboxylate esters. evidence for stereospecific oxygen atom transfer in a nucleophilic epoxidation Process
Svenda, Jakub,Myers, Andrew G.
supporting information; experimental part, p. 2437 - 2440 (2009/11/30)
Methyl r-methylene-β-tert-butyldimethylsilyloxycarboxylate esters are found to undergo diastereoselective epoxidation in the presence of potassium tert-butoxide-tert-butyl hydroperoxide to form anti products. In an effort to better understand mechanistic
