1145681-79-3Relevant academic research and scientific papers
Stereocontrolled O -glycosylation with palladium-catalyzed decarboxylative allylation
Xiang, Shaohua,He, Jingxi,Tan, Yu Jia,Liu, Xue-Wei
, p. 11473 - 11482 (2014)
The Pd-π-allyl intermediate in an electron-rich glycal system with poor reactivity is employed as an efficient glycosyl donor. Starting from glucal derived carbonate, various O-glycosides were formed via a palladium-catalyzed reaction through a tandem decarboxylation, proton abstraction, and nucleophilic addition, in good yields with excellent selectivity. Iterative glycosylation with the same strategy may provide an access to complex oligosaccharides.
Kinetically controlled Ferrier rearrangement of 3-O-mesyl-d-glycal derivatives
Watanabe, Yuhya,Itoh, Tsubasa,Sakakibara, Tohru
experimental part, p. 516 - 520 (2009/05/11)
The Ferrier rearrangement, which is widely used in carbohydrate chemistry, is generally performed under acidic conditions to give an α anomer with high stereoselectivity. We have found that 3-O-mesyl-d-glycals 2-4 were smoothly reacted with alcohols in th
