1145685-38-6Relevant articles and documents
A palladium-nanoparticle and silicon-nanowire-array hybrid: A platform for catalytic heterogeneous reactions
Yamada, Yoichi M. A.,Yuyama, Yoshinari,Sato, Takuma,Fujikawa, Shigenori,Uozumi, Yasuhiro
, p. 127 - 131 (2014)
We report the development of a silicon nanowire array-stabilized palladium nanoparticle catalyst, SiNA-Pd. Its use in the palladium-catalyzed Mizoroki-Heck reaction, the hydrogenation of an alkene, the hydrogenolysis of nitrobenzene, the hydrosilylation of an α,β-unsaturated ketone, and the C-H bond functionalization reactions of thiophenes and indoles achieved a quantitative production with high reusability. The catalytic activity reached several hundred-mol ppb of palladium, reaching a TON of 2 000 000. An array of reactions: A silicon-nanowire-array-stabilized palladium-nanoparticle catalyst, SiNA-Pd, was designed and used in the palladium-catalyzed Mizoroki-Heck reaction. It can catalyze a variety of other reactions and has a high reusability. Copyright