1145688-80-7

Upstream product

• 67-64-1 acetone 
• 97-51-8 5-Nitrosalicylaldehyde 
• 5627-11-2 1,2-bis(aminooxy)ethane 

Relevant academic research and scientific papers

Three new Salamo-type homotrinuclear nickel(II) complexes possessing solvent effects: Syntheses, structures and fluorescence properties

Three new solvent-induced Ni(II) complexes with the chemical formulae [{Ni(L)(CH3OH)}2(μ-OAc)2Ni] (1), [{Ni(L)(C3H7OH)}2(μ-OAc)2Ni] (2) and [{NiL(H2O)}2(μ-O

Synthesis, crystal structure, luminescence and electrochemical properties of a Salamo-type trinuclear cobalt(II) complex

A trinuclear Co(II) complex, [{CoL(C4H9OH)}2-(OAc)2Co]·C3H7NO, was synthesized by the reaction of a Salamo-type chelating ligand (H2L=4,42′-dinitro-2,2′-[1,2-ethylenedioxybis(nit

Oxime-based salen-type tetradentate ligands with high stability against imine metathesis reaction

(Chemical Equation Presented) Although salen and its analogues are versatile chelate ligands in inorganic and organometallic chemistry, synthesis of unsymmetrical salen derivatives consisting of two different salicylideneimine moieties is difficult becaus

Two novel copper(II) salamo-based complexes: Syntheses, X-ray crystal structures, spectroscopic properties and Hirshfeld surfaces analyses

Two novel Cu(II) complexes, [{Cu(L1)}2(CH3OH)]·CH3OH (1) and [Cu(L2)2] (2) derived from a half-salamo-based N2O-donor ligand (HL: 2-[O-(1-ethyloxyamide)]oxime-4-nitrophenol) were synthesized and characterized by elemental analyses, infrared spectroscopy, ultraviolet–visible absorption spectroscopy, X-ray single crystal diffraction and Hirshfeld surfaces analyses. Here, ligands H2L1 (4,4′-Dinitro-2,2′-[ethylenedioxybis(nitrilomethylidyne)]diphenol) and HL2 ((E)-2-Hydroxy-5-nitrobenzaldehyde O-(2-((propan-2-ylideneamino)oxy)ethyl) oxime) are obtained by rearrangement reaction due to the catalysis of Cu(II) ion during the formation of the complexes 1 and 2. The complex 1 consists of two Cu(II) ions, two fully deprotonated ligand (L1)? units, one coordinated methanol and one crystallized methanol molecules, forming an novel unsymmetric dinuclear structure previously unreported, and possesses an infinite 3D supramolecular structure. The Cu(II) ions are penta-coordinated and with distorted tetragonal pyramidal geometric configuration. The complex 2 is an novel symmetric mononuclear structure, consists of one Cu(II) ion, two fully deprotonated ligand (L2)? units, forming a four-coordinated planar quadrilateral geometric configuration with a Cu(II) ion occupying the center of symmetry, and possesses an infinite 2D supramolecular structure. Simultaneously, the fluorescence properties and Hirshfeld surfaces analyses of the Cu(II) complexes 1 and 2 were also investigated.

Synthesis and characterization of nitro salamo-type Bisoxime compounds

A series of nitro salamo-type bisoxime compounds have been synthesized from 2-hydroxy-5-nitrobenzaldehyde and 1,2-bis(aminooxy)- ethane, 1,3-bis(aminooxy)propane, 1,4-bis(aminooxy)butane or 1,5-bis(aminooxy)pentane in ethanol medium, respectively and characterized by elemental analyses as well as IR, UV-visible and 1H NMR spectroscopy.