114580-99-3Relevant academic research and scientific papers
Unprecedented transformation of a vinylidene ligand. Synthesis and ESR characterization of a paramagnetic σ-acetylide complex of rhodium(II)
Bianchini, Claudio,Laschi, Franco,Ottaviani, Francesca,Peruzzini, Maurizio,Zanello, Piero
, p. 1660 - 1661 (2008/10/08)
Thermal decomposition in THF of the diamagnetic vinylidene complex [(np3)RhC=C(H)Ph]+, obtained by protonation of [(np3)RhC≡CPh], affords H2 and the paramagnetic σ-acetylide complex of rhodium(II) [(np3)RhC≡CPh]+ which has been characterized by chemical, electrochemical, and ESR techniques [np3 = N(CH2CH2PPh2)3].
