114630-33-0Relevant academic research and scientific papers
Novel Catalysts for the Carbonylation of Methanol
Dilworth, Jonathan R.,Miller, John R.,Wheatley, Nigel,Baker, Michael J.,Sunley, J. Glenn
, p. 1579 - 1582 (1995)
Rhodium(I) carbonyl complexes containing phosphino-thiolate and -thioether ligands are almost four times as active in catalysing the carbonylation of methanol to ethanoic acid as the previously known catalyst, -; the crystal structure of one procatalyst, 2, is reported.
Platinum and rhodium complexes in which diphenylphosphino(methylthio)methane acts as a monodentate, chelated or bridging ligand
Anderson, Gordon K.,Kumar, Ravi
, p. 263 - 268 (2007/10/02)
Reaction of with Ph2PCH2SCH3 yields cis- which, on treatment with AgBF4, is converted to BF4, in which one of the ligands is chelated.With , cis- reacts to give the platinum(I) complex , which contains a platinum-platinum bond.The terminal chlorides may be replaced by iodide, but the complex is cleaved by carbon monoxide. reacts with Ph2PCH2SCH3 to produce , whereas with Ph2PCH2CH2SCH3 it yields .A ligand exchange reaction occurs between cis- and to give cis- and .
