1146352-92-2Relevant academic research and scientific papers
Synthetic studies on daphnicyclidin A: enantiocontrolled construction of the BCD ring system
Ikeda, Shuhei,Shibuya, Masatoshi,Kanoh, Naoki,Iwabuchi, Yoshiharu
, p. 1833 - 1836 (2009)
An enantiocontrolled entry to the tricyclic core of daphnicyclidin A with five chlral centers Including an all-carbon quaternary center Is reported. The synthesis features a highly dlastereoselectlve conjugate addition of nltromethane, an Ireland- Clalsen rearrangement, and a tandem acyliminium/ Mannich- type reaction.
