114656-16-5

Upstream product

• 114644-83-6 2-(6-benzoyloxymethyl-2,4-dibenzyloxyphenyl)-6-vinyl-2,3-dihydro-4H-pyran-4-one 
• 114644-82-5 2-(6-benzoyloxymethyl-2,4-dibenzyloxyphenyl)-2,3-dihydro-4H-pyran-4-one 
• 114644-81-4 6-benzoyloxymethyl-2,4-dibenzyloxybenzaldehyde 
• 114644-80-3 (3,5-dibenzyloxyphenyl)methyl benzoate 
• 98-88-4 benzoyl chloride 
• 24131-31-5 3,5-dibenzyloxybenzyl alcohol 
• 99-10-5 3,5-Dihydroxybenzoic acid 
• 58605-10-0 methyl 3,5-bis(benzyloxy)benzoate 
• 2150-44-9 1-carbomethoxy-3,5-dihydroxybenzene 
• 114644-85-8 Benzoic acid 3,5-bis-benzyloxy-2-((2S,6S)-6-formyl-4-oxo-tetrahydro-pyran-2-yl)-benzyl ester 

Downstream Products

• 114644-97-2 (3R,4S,5S,6R)-2-(2,4-Bis-benzyloxy-6-hydroxymethyl-phenyl)-6-hydroxymethyl-2-methoxy-tetrahydro-pyran-3,4,5-triol 
• 114644-90-5 C₄₈H₄₀O₁₀ 
• 114644-89-2 3-benzoyloxy-2-benzoyloxymethyl-6-(6-benzoyloxymethyl-2,4-dibenzyloxyphenyl)-2,3-dihydro-4H-pyran-one 
• 114644-88-1 trans-5-benzoyloxy-6-benzoyloxymethyl-2-(6-benzoyloxymethyl-2,4-dibenzyloxyphenyl)-2,3,5,6-tetrahydro-4H-pyran-4-one 
• 114644-91-6 <2-(3-acetyl-1,5-anhydro-4,6-di-O-benzoyl-2-deoxy-DL-arabino-hex-1-enit-3-yl)-3,5-dibenzoyloxyphenyl>methyl benzoate 
• 114644-95-0 C₅₁H₄₈O₁₀Si 
• 114644-92-7 <3,5-dibenzoyloxy-2-(methyl-3-O-acetyl-4,6-di-O-benzoyl-DL-glucopyuranosid-1-yl)phenyl>methyl benzoate 
• 114644-86-9 6-benzoyloxymethyl-2-(6-benzoyloxymethyl-2,4-dibenzoyloxyphenyl)-2,3,5,6-tetrahydro-4H-pyran-4-one 

Relevant academic research and scientific papers

A FULLY SYNTHETIC ROUTE TO THE PAPULACANDINS. STEREOSPECIFIC SPIROACETALIZATION OF A C-1-ARYLATED METHYLGLYCOSIDE

Lewis acid-catalyzed, hetero Diels-Alder reaction of (E)-1-methoxy-3-trimethylsilyloxy-1,3-butadiene, with 6-benzoyloxymethyl-2,4-dibenzyloxy benzaldehyde afforded 2-(6-benzoyloxymethyl-2,4-dibenzyloxyphenyl)-2,3-dihydro-4H-pyran-4-one.This was converted into a derivative of papulacandin D by a stereospecific, spiroacetalization of a C-1 methoxylated aryl glycoside, methyl benzoate.