114663-08-0Relevant articles and documents
Structure Determination of Unusual Rearrangement Products of S-(1-Alkenyl)sulfoximides by Collisionally Activated Dissociation Mass Spectrometry (CAD-MS)
Veith, Hans-Juergen von,Gais, Hans-Joachim,Erdelmeier, Irene
, p. 1041 - 1049 (1987)
The molecular ions of S-(1-alkenyl)-N-sulfoximides 1 are transformed into the N-(phenylsulfenyl)sulfonamides 3+. by a 1,2-migration of the alkenyl group to the O-atom of the sulfoximide function followed by a 2,3-sigmatropic