Structure Determination of Unusual Rearrangement Products of S-(1-Alkenyl)sulfoximides by Collisionally Activated Dissociation Mass Spectrometry (CAD-MS)

DOI: 10.1002/hlca.19870700416

Source and publish data:

Helvetica Chimica Acta p. 1041 - 1049 (1987)

Update date:2022-07-29

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Authors:

Veith, Hans-Juergen von

Gais, Hans-Joachim

Erdelmeier, Irene

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Article abstract of DOI:10.1002/hlca.19870700416

The molecular ions of S-(1-alkenyl)-N-<(p-tolyl)sulfonyl>sulfoximides 1 are transformed into the N-(phenylsulfenyl)sulfonamides 3^+. by a 1,2-migration of the alkenyl group to the O-atom of the sulfoximide function followed by a 2,3-sigmatropic

Full text of DOI:10.1002/hlca.19870700416

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