114671-09-9

Basic information

• Product Name: N-(tert-butyldimethylsilyloxycarbonyl)-4-amino-1-chloro-5-phenyl-2-pentene
• Synonyms: N-(tert-butyldimethylsilyloxycarbonyl)-4-amino-1-chloro-5-phenyl-2-pentene
• CAS NO: 114671-09-9
• Molecular Weight: 353.964
• Mol File: 114671-09-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N-(tert-butyldimethylsilyloxycarbonyl)-4-amino-1-chloro-5-phenyl-2-pentene(CAS DataBase Reference)
• NIST Chemistry Reference: N-(tert-butyldimethylsilyloxycarbonyl)-4-amino-1-chloro-5-phenyl-2-pentene(114671-09-9)
• EPA Substance Registry System: N-(tert-butyldimethylsilyloxycarbonyl)-4-amino-1-chloro-5-phenyl-2-pentene(114671-09-9)

Safety Data

• Hazardous Substances Data: 114671-09-9(Hazardous Substances Data)

Upstream product

• 72155-45-4 Boc-L-phenylalaninal 
• 66605-57-0 (S)-N-tert-butoxycarbonyl-2-amino-3-phenylpropanol 
• 124818-94-6 ethyl (2E,4S)-4-[(tert-butoxycarbonyl)amino]-5-phenylpent-2-enoate 
• 124818-93-5 (4S)-4-(N-tert-butoxycarbonyl)amino-5-phenyl-2-penten-1-ol 
• 69739-34-0 t-butyldimethylsiyl triflate 
• 124818-81-1 (4S)-N-(tert-botoxycarbonyl)-4-amino-1-chloro-5-phenyl-2-pentene 

Downstream Products

• 124754-71-8 (4S,5S)-4-benzyl-5-(2-hydroxyethyl)-2-oxazolidinone 
• 109389-15-3 N-(tert-Butyloxycarbonyl)-4(S)-amino-3(S)-hydroxy-5-phenylpentanol 
• 72155-48-7 (3S,4S)-4-tert-butoxycarbonylamino-3-hydroxy-5-phenylpentanoic acid 
• 885859-80-3 (3S,4S)-4-Amino-5-phenyl-pentane-1,3-diol 
• 114671-12-4 (4S,5S)-5-ethenyl-4-phenylmethyloxazolidin-2-one 
• 124915-64-6 (4S,5R)-5-ethenyl-4-phenylmethyloxazolidin-2-one 

Relevant articles and documents

Syntheses and reactions of silyl carbamates. 2. A new mode of cyclic carbamate formation from tert-butyldimethylsilyl carbamate

Stereoselective construction of 1,2 and 1,3 amino hydroxyl systems was achieved by the intramolecular trapping of the N-tert-butyldimethylsilyloxycarbonyl species (silyl carbamate) activated by fluoride ion. The reaction of the silyl carbamate with 1,2-sy