114675-88-6

Basic information

• Product Name: Acetic acid, [[(2-nitrophenyl)thio]imino]-, methyl ester, (E)-
• CAS NO: 114675-88-6
• Molecular Formula: C9H8N2O4S
• Molecular Weight: 240.24
• Mol File: 114675-88-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Acetic acid, [[(2-nitrophenyl)thio]imino]-, methyl ester, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid, [[(2-nitrophenyl)thio]imino]-, methyl ester, (E)-(114675-88-6)
• EPA Substance Registry System: Acetic acid, [[(2-nitrophenyl)thio]imino]-, methyl ester, (E)-(114675-88-6)

Safety Data

• Hazardous Substances Data: 114675-88-6(Hazardous Substances Data)

Upstream product

• 14608-72-1 N-(2-nitro-benzenesulfenyl)-glycine methyl ester 
• 109745-70-2 methyl glyoxylate methyl hemi-acetal 
• 7257-59-2 2-nitrobenzenesulfenamide 
• 7669-54-7 2-nitrobenzenesulfenyl chloride 
• 114675-78-4 o-nitrophenylsulfenyl-L-threonine methyl ester 
• 114675-77-3 3-Hydroxy-2-(2-nitro-phenylsulfanylamino)-propionic acid methyl ester 

Downstream Products

• 1031436-73-3 methyl N-(2-nitrobenzenesulfenyl)(3-indolyl)glycinate 

Relevant articles and documents

Synthesis of enantiopure (S)-indolylglycine by organocatalyzed Friedel-Crafts alkylation of indole

Tritylsulfenyl- and 2-nitrophenylsulfenyl-substituted glyoxyl imines were used in chiral phosphoric acid catalyzed Friedel-Crafts (FC) reactions with indole. High yields and ee values ranging from 86 % for Nps-protected (S)-indolylglycine to 88 % for Trs-